Organic solar cells (OSCs) have attracted significant attention due to their potential of large area solution fabrication capability at low-cost. For bulk heterojunction (BHJ) OSCs, a thin film of transparent conducting indium tin oxide (ITO), coated on glass or flexible plastic substrate, is widely used as a front electrode. However, indium is not abundant on Earth. Its price has increased continuously over the past 10 years and will likely become an obstacle for the commercialization of OSCs at low cost. Aluminum-doped zinc oxide (AZO) is a promising ITO alternative due to its advantages of high electric conductivity, optical transparency, non-toxicity and low cost. However, reports on OSCs using AZO electrode are quite limited, due to the relatively lower power conversion efficiency (PCE) of AZO-based OCSs as compared to that of ITO-based OCSs. This work focused on studies of high performance AZO-based OSCs through AZO surface modification, absorption enhancement and process optimization. The optical and electronic properties of AZO film including transmittance, sheet resistance, surface morphology and surface work function were characterized. AZO-based OSCs with conventional and inverted structures were fabricated. It was found that AZO-based OSCs with inverted structure demonstrated superior performance than the ones with conventional structure. The inverted structure avoids the use of acidic PEDOT:PSS hole transporting layer, allows the improving of the absorbance of the OSCs and therefore its efficiency. An AZO front transparent cathode was used for application in high performance inverted BHJ OSCs. The photoactive layer consisted a blend of poly[[4,8-bis[(2- ethylhexyl)oxy] benzo [1,2-b:4,5-b'] dithiophene-2,6- diyl][3-fluoro- 2-[(2-ethylhexyl) carbonyl]thieno[3,4-b]thiophenediyl]](PTB7):3'H-Cyclopropa[8,25][5,6]fullerene- C70- D5h(6)-3'-butanoicacid, 3'-phenyl-, methyl ester (PC70BM). A structurally identical control OSC having an ITO front cathode was also fabricated for comparison studies. The structure of OSCs was optimized to achieving absorption enhancement in the active layer. AZO and ITO were modified with a 10 nm thick solution-processed ZnO interlayer to facilitate the efficient electron extraction. The results revealed that bilayer AZO/ZnO and the ITO/ZnO cathodes possess similar electron extraction property. AZO layer has a transparency cutoff at wavelength < 380 nm, results in a slight decrease in the short-circuit current density (JSC). However, the decrease in JSC is very small because the main energy of solar irradiation falls in the spectrum with wavelength > 380 nm. It shows that AZO-based OSCs have a promising PCE of 6.15%, which is slightly lower than that of a control ITO-based OSC (6.57%). AZO-based OSCs, however, demonstrate an obvious enhancement in the stability under an ultraviolet (UV)-assisted acceleration aging test. The significant enhancement in the stability of AZO-based OSCs arises from the tailored absorption of AZO electrode in wavelength < 380 nm, which serves as a UV filter to inhibit an inevitable degradation process in ITO-based OSCs due to the UV irradiation. In order to further investigate the degradation mechanism of OSCs under UV exposure, the change in charge collection characteristics of the OSCs made with ITO/ZnO and AZO/ZnO front cathode before and after UV exposure was examined. It was found that there was an obvious decrease in the charge extraction efficiency of ITO-based OSCs after UV exposure, while there was no observable change in the charge extraction efficiency of OSCs made with AZO/ZnO cathode under the same acceleration aging test. This work demonstrates that AZO is a suitable ITO alternative for application in OSCs, offering an improved device stability, comparable PCE and cell fabrication processes with an attractive commercial potential.
|Date of Award||20 Aug 2014|
|Supervisor||Fu Rong ZHU (Supervisor)|
- Solar cells
- Transparent semiconductors
- Zinc oxide thin films