White organic light-emitting diodes with evenly separated red, green, and blue colors for efficiency/color-rendition trade-off optimization

Shuming Chen, Guiping Tan, Wai Yeung WONG*, Hoi Sing Kwok

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

153 Citations (Scopus)

Abstract

A novel yellowish-green triplet emitter, bis(5-(trifluoromethyl)-2-p- tolylpyridine) (acetylacetonate)iridium(III) (1), was conveniently synthesized and used in the fabrication of both monochromatic and white organic light-emitting diodes (WOLEDs). At the optimal doping concentration, monochromatic devices based on 1 exhibit a high efficiency of 63 cd A -1 (16.3% and 36.6 lm W-1) at a luminance of 100 cd m -2. By combining 1 with a phosphorescent sky-blue emitter, bis(3,5-difluoro-2-(2-pyridyl)phenyl)-(2-carboxypyridyl)iridium(III) (FIrPic), and a red emitter, bis(2-benzo[b]thiophen-2-yl-pyridine)(acetylacetonate) iridium(III) (Ir(btp)2(acac)), the resulting electrophosphorescent WOLEDs show three evenly separated main peaks and give a high efficiency of 34.2 cd A-1 (13.2% and 18.5 lm W-1) at a luminance of 100 cd m-2. When 1 is mixed with a deep-blue fluorescent emitter, 4,4′-bis(9-ethyl-3-carbazovinylene)-1,1′-biphenyl (BCzVBi), and Ir(btp)2(acac), the resulting hybrid WOLEDs demonstrate a high color-rendering index of 91.2 and CIE coordinates of (0.32, 0.34). The efficient and highly color-pure WOLEDs based on 1 with evenly separated red, green, blue peaks and a high color-rendering index outperform those of the state-of-the-art emitter, fac-tris(2-phenylpyridine)iridium(III) (Ir(ppy)3), and are ideal candidates for display and lighting applications.

Original languageEnglish
Pages (from-to)3785-3793
Number of pages9
JournalAdvanced Functional Materials
Volume21
Issue number19
DOIs
Publication statusPublished - 7 Oct 2011

Scopus Subject Areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

User-Defined Keywords

  • emitters
  • high color-rendering indices
  • multiple emission peaks
  • phosphorescent dyes
  • white organic light-emitting diodes (WOLEDs)

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