Visible light-induced oxidative N-dealkylation of alkylamines by a luminescent osmium(VI) nitrido complex

Jing Xiang; Min Peng; Yi Pan; Li-Juan Luo; Shun-Cheung Cheng; Xin-Xin Jin; Shek-Man Yiu; Wai-Lun Man; Chi-Chiu Ko; Kai-Chung Lau; Tai-Chu Lau

doi:10.1039/d1sc04369b

Visible light-induced oxidative N-dealkylation of alkylamines by a luminescent osmium(VI) nitrido complex

Jing Xiang
, Min Peng
, Yi Pan
, Li-Juan Luo
, Shun-Cheung Cheng
, Xin-Xin Jin
, Shek-Man Yiu
, Wai-Lun Man
, Chi-Chiu Ko
, Kai-Chung Lau^*
, Tai-Chu Lau^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

20 Citations (Scopus)

Abstract

N-Dealkylation of amines by metal oxo intermediates (M=O) is related to drug detoxification and DNA repair in biological systems. In this study, we report the first example of N-dealkylation of various alkylamines by a luminescent osmium(VI) nitrido complex induced by visible light.

Original language	English
Pages (from-to)	14494-14498
Number of pages	5
Journal	Chemical Science
Volume	12
Issue number	43
Early online date	9 Oct 2021
DOIs	https://doi.org/10.1039/d1sc04369b
Publication status	Published - 21 Nov 2021

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10.1039/d1sc04369b

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title = "Visible light-induced oxidative N-dealkylation of alkylamines by a luminescent osmium(VI) nitrido complex",

abstract = "N-Dealkylation of amines by metal oxo intermediates (M=O) is related to drug detoxification and DNA repair in biological systems. In this study, we report the first example of N-dealkylation of various alkylamines by a luminescent osmium(VI) nitrido complex induced by visible light.",

author = "Jing Xiang and Min Peng and Yi Pan and Li-Juan Luo and Shun-Cheung Cheng and Xin-Xin Jin and Shek-Man Yiu and Wai-Lun Man and Chi-Chiu Ko and Kai-Chung Lau and Tai-Chu Lau",

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T1 - Visible light-induced oxidative N-dealkylation of alkylamines by a luminescent osmium(VI) nitrido complex

AU - Xiang, Jing

AU - Peng, Min

AU - Pan, Yi

AU - Luo, Li-Juan

AU - Cheng, Shun-Cheung

AU - Jin, Xin-Xin

AU - Yiu, Shek-Man

AU - Man, Wai-Lun

AU - Ko, Chi-Chiu

AU - Lau, Kai-Chung

AU - Lau, Tai-Chu

PY - 2021/11/21

Y1 - 2021/11/21

N2 - N-Dealkylation of amines by metal oxo intermediates (M=O) is related to drug detoxification and DNA repair in biological systems. In this study, we report the first example of N-dealkylation of various alkylamines by a luminescent osmium(VI) nitrido complex induced by visible light.

AB - N-Dealkylation of amines by metal oxo intermediates (M=O) is related to drug detoxification and DNA repair in biological systems. In this study, we report the first example of N-dealkylation of various alkylamines by a luminescent osmium(VI) nitrido complex induced by visible light.

U2 - 10.1039/d1sc04369b

DO - 10.1039/d1sc04369b

M3 - Journal article

SN - 2041-6520

VL - 12

SP - 14494

EP - 14498

JO - Chemical Science

JF - Chemical Science

IS - 43

ER -

Visible light-induced oxidative N-dealkylation of alkylamines by a luminescent osmium(VI) nitrido complex

Abstract

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