Visible light-induced oxidative N-dealkylation of alkylamines by a luminescent osmium(VI) nitrido complex

Jing Xiang, Min Peng, Yi Pan, Li-Juan Luo, Shun-Cheung Cheng, Xin-Xin Jin, Shek-Man Yiu, Wai-Lun Man, Chi-Chiu Ko, Kai-Chung Lau*, Tai-Chu Lau*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

N-Dealkylation of amines by metal oxo intermediates (M=O) is related to drug detoxification and DNA repair in biological systems. In this study, we report the first example of N-dealkylation of various alkylamines by a luminescent osmium(VI) nitrido complex induced by visible light.
Original languageEnglish
Pages (from-to)14494-14498
Number of pages5
JournalChemical Science
Volume12
Issue number43
Early online date9 Oct 2021
DOIs
Publication statusPublished - 21 Nov 2021

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