TY - JOUR
T1 - Vanadium Oxide
T2 - Phase Diagrams, Structures, Synthesis, and Applications
AU - Hu, Peng
AU - Hu, Ping
AU - Vu, Tuan Duc
AU - Li, Ming
AU - Wang, Shancheng
AU - Ke, Yujie
AU - Zeng, Xianting
AU - Mai, Liqiang
AU - Long, Yi
N1 - Peng Hu acknowledges the financial support from the National Natural Science Foundation of China (No. 51803168), the Key Research and Development Program of Shaanxi Province (2022GY-356), and the Youth Innovation Team of Shaanxi Universities. L.M. acknowledges the financial support from the National Key Research and Development Program of China (Grant No. 2020YFA0715000), the National Natural Science Foundation of China (Grant No. 52127816), and the Foshan Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory (XHT2020-003). Ping Hu acknowledges the financial support from the Guangdong Basic and Applied Basic Research Foundation (2021A1515110059). Y.L. would like to acknowledge the funding support from MOE-T2EP50221-0014, Ministry of Education, Singapore. Y.L. would like to acknowledge the funding support from MOE-T2EP50221-0014, Minster of Education, Singapore and Global STEM Professorship Scheme sponsored by the Government of the Hong Kong Special Administrative Region.
Publisher Copyright:
© 2023 The Authors. Published by American Chemical Society.
PY - 2023/4/26
Y1 - 2023/4/26
N2 - Vanadium oxides with multioxidation states and various crystalline structures offer unique electrical, optical, optoelectronic and magnetic properties, which could be manipulated for various applications. For the past 30 years, significant efforts have been made to study the fundamental science and explore the potential for vanadium oxide materials in ion batteries, water splitting, smart windows, supercapacitors, sensors, and so on. This review focuses on the most recent progress in synthesis methods and applications of some thermodynamically stable and metastable vanadium oxides, including but not limited to V2O3, V3O5, VO2, V3O7, V2O5, V2O2, V6O13, and V4O9. We begin with a tutorial on the phase diagram of the V-O system. The second part is a detailed review covering the crystal structure, the synthesis protocols, and the applications of each vanadium oxide, especially in batteries, catalysts, smart windows, and supercapacitors. We conclude with a brief perspective on how material and device improvements can address current deficiencies. This comprehensive review could accelerate the development of novel vanadium oxide structures in related applications.
AB - Vanadium oxides with multioxidation states and various crystalline structures offer unique electrical, optical, optoelectronic and magnetic properties, which could be manipulated for various applications. For the past 30 years, significant efforts have been made to study the fundamental science and explore the potential for vanadium oxide materials in ion batteries, water splitting, smart windows, supercapacitors, sensors, and so on. This review focuses on the most recent progress in synthesis methods and applications of some thermodynamically stable and metastable vanadium oxides, including but not limited to V2O3, V3O5, VO2, V3O7, V2O5, V2O2, V6O13, and V4O9. We begin with a tutorial on the phase diagram of the V-O system. The second part is a detailed review covering the crystal structure, the synthesis protocols, and the applications of each vanadium oxide, especially in batteries, catalysts, smart windows, and supercapacitors. We conclude with a brief perspective on how material and device improvements can address current deficiencies. This comprehensive review could accelerate the development of novel vanadium oxide structures in related applications.
UR - http://www.scopus.com/inward/record.url?scp=85151387180&partnerID=8YFLogxK
UR - https://pubs.acs.org/doi/10.1021/acs.chemrev.2c00546
U2 - 10.1021/acs.chemrev.2c00546
DO - 10.1021/acs.chemrev.2c00546
M3 - Review article
C2 - 36972332
AN - SCOPUS:85151387180
SN - 0009-2665
VL - 123
SP - 4353
EP - 4415
JO - Chemical Reviews
JF - Chemical Reviews
IS - 8
ER -
