Unusual iron(II) and cobalt(II) complexes derived from monodentate arylamido ligands

Yu Au Yeung Ho; Hei Lam Chung; Chi Keung Lam; Wai Yeung Wong; Kay Lee Hung

doi:10.1021/ic700850e

Unusual iron(II) and cobalt(II) complexes derived from monodentate arylamido ligands

Yu Au Yeung Ho
, Hei Lam Chung
, Chi Keung Lam
, Wai Yeung Wong
, Kay Lee Hung^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

31 Citations (Scopus)

Abstract

The coordination chemistry of the N-substituted arylamido ligands [N(R)(C₆H₃R′₂-2,6)] [R = SiMe ₃, R′ = Me (L¹); R = CH₂Bu^t, R′ = Pr^j (L²)] toward Fe^II and Co ^II ions was studied. The monoamido complexes [M(L¹)(Cl) (tmeda)] [M = Fe (1), Co (2)] react readily with MeLi, affording the mononuclear, paramagnetic iron(II) and cobalt(II) methyl-arylamido complexes [M(L¹)(Me)(tmeda)] [M = Fe (3), Co (4)]. Treatment of 2:1 [Li(L ²)(THF)₂]/FeCl₂ affords the unusual two-coordinate iron(II) bis(arylamide) [Fe(L²)₂] (5).

Original language	English
Pages (from-to)	7695-7697
Number of pages	3
Journal	Inorganic Chemistry
Volume	46
Issue number	19
DOIs	https://doi.org/10.1021/ic700850e
Publication status	Published - 17 Sept 2007

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@article{fff60642ec7443a79324a43614c93036,

title = "Unusual iron(II) and cobalt(II) complexes derived from monodentate arylamido ligands",

abstract = "The coordination chemistry of the N-substituted arylamido ligands [N(R)(C6H3R′2-2,6)] [R = SiMe 3, R′ = Me (L1); R = CH2But, R′ = Prj (L2)] toward FeII and Co II ions was studied. The monoamido complexes [M(L1)(Cl) (tmeda)] [M = Fe (1), Co (2)] react readily with MeLi, affording the mononuclear, paramagnetic iron(II) and cobalt(II) methyl-arylamido complexes [M(L1)(Me)(tmeda)] [M = Fe (3), Co (4)]. Treatment of 2:1 [Li(L 2)(THF)2]/FeCl2 affords the unusual two-coordinate iron(II) bis(arylamide) [Fe(L2)2] (5).",

author = "Ho, \{Yu Au Yeung\} and Chung, \{Hei Lam\} and Lam, \{Chi Keung\} and Wong, \{Wai Yeung\} and Hung, \{Kay Lee\}",

note = "The Chinese University of Hong Kong for financial support of this work in the form of a Direct Grant (A/C 2060253) and a postgraduate studentship to H.Y.A.-Y. ",

year = "2007",

month = sep,

day = "17",

doi = "10.1021/ic700850e",

language = "English",

volume = "46",

pages = "7695--7697",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

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TY - JOUR

T1 - Unusual iron(II) and cobalt(II) complexes derived from monodentate arylamido ligands

AU - Ho, Yu Au Yeung

AU - Chung, Hei Lam

AU - Lam, Chi Keung

AU - Wong, Wai Yeung

AU - Hung, Kay Lee

N1 - The Chinese University of Hong Kong for financial support of this work in the form of a Direct Grant (A/C 2060253) and a postgraduate studentship to H.Y.A.-Y.

PY - 2007/9/17

Y1 - 2007/9/17

N2 - The coordination chemistry of the N-substituted arylamido ligands [N(R)(C6H3R′2-2,6)] [R = SiMe 3, R′ = Me (L1); R = CH2But, R′ = Prj (L2)] toward FeII and Co II ions was studied. The monoamido complexes [M(L1)(Cl) (tmeda)] [M = Fe (1), Co (2)] react readily with MeLi, affording the mononuclear, paramagnetic iron(II) and cobalt(II) methyl-arylamido complexes [M(L1)(Me)(tmeda)] [M = Fe (3), Co (4)]. Treatment of 2:1 [Li(L 2)(THF)2]/FeCl2 affords the unusual two-coordinate iron(II) bis(arylamide) [Fe(L2)2] (5).

AB - The coordination chemistry of the N-substituted arylamido ligands [N(R)(C6H3R′2-2,6)] [R = SiMe 3, R′ = Me (L1); R = CH2But, R′ = Prj (L2)] toward FeII and Co II ions was studied. The monoamido complexes [M(L1)(Cl) (tmeda)] [M = Fe (1), Co (2)] react readily with MeLi, affording the mononuclear, paramagnetic iron(II) and cobalt(II) methyl-arylamido complexes [M(L1)(Me)(tmeda)] [M = Fe (3), Co (4)]. Treatment of 2:1 [Li(L 2)(THF)2]/FeCl2 affords the unusual two-coordinate iron(II) bis(arylamide) [Fe(L2)2] (5).

UR - https://www.scopus.com/pages/publications/34948890498

U2 - 10.1021/ic700850e

DO - 10.1021/ic700850e

M3 - Journal article

AN - SCOPUS:34948890498

SN - 0020-1669

VL - 46

SP - 7695

EP - 7697

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 19

ER -

Unusual iron(II) and cobalt(II) complexes derived from monodentate arylamido ligands

Abstract

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