Tunable chiral monophosphines as ligands in enantioselective rhodium-catalyzed ring-opening of oxabenzonorbornadienes with amines

Renshi Luo; Ling Xie; Jianhua Liao; Hu Xin; Albert S.C. Chan

doi:10.1016/j.tetasy.2014.03.017

Tunable chiral monophosphines as ligands in enantioselective rhodium-catalyzed ring-opening of oxabenzonorbornadienes with amines

Renshi Luo^*
, Ling Xie
, Jianhua Liao
, Hu Xin
, Albert S.C. Chan

^*Corresponding author for this work

Research output: Contribution to journal › Journal article › peer-review

21 Citations (Scopus)

Abstract

A new tunable chiral monophosphine was used as a ligand for asymmetric rhodium-catalyzed ring-opening of oxabenzonorbornadiene with amines, providing a series of chiral ring-opened products in high yields (up to 97%) and with high enantioselectivities (>99%).The reaction can be performed at rt to obtain the desired product with high enantioselectivity.

Original language	English
Pages (from-to)	709-717
Number of pages	9
Journal	Tetrahedron Asymmetry
Volume	25
Issue number	9
DOIs	https://doi.org/10.1016/j.tetasy.2014.03.017
Publication status	Published - 15 May 2014

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10.1016/j.tetasy.2014.03.017

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title = "Tunable chiral monophosphines as ligands in enantioselective rhodium-catalyzed ring-opening of oxabenzonorbornadienes with amines",

abstract = "A new tunable chiral monophosphine was used as a ligand for asymmetric rhodium-catalyzed ring-opening of oxabenzonorbornadiene with amines, providing a series of chiral ring-opened products in high yields (up to 97\%) and with high enantioselectivities (>99\%).The reaction can be performed at rt to obtain the desired product with high enantioselectivity.",

author = "Renshi Luo and Ling Xie and Jianhua Liao and Hu Xin and Chan, \{Albert S.C.\}",

note = "We are grateful to the start fund of the School of Pharmaceutical Sciences, Gannan Medical University (QD201303). Publisher copyright: {\textcopyright} 2014 Elsevier Ltd. All rights reserved.",

year = "2014",

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doi = "10.1016/j.tetasy.2014.03.017",

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T1 - Tunable chiral monophosphines as ligands in enantioselective rhodium-catalyzed ring-opening of oxabenzonorbornadienes with amines

AU - Luo, Renshi

AU - Xie, Ling

AU - Liao, Jianhua

AU - Xin, Hu

AU - Chan, Albert S.C.

PY - 2014/5/15

Y1 - 2014/5/15

N2 - A new tunable chiral monophosphine was used as a ligand for asymmetric rhodium-catalyzed ring-opening of oxabenzonorbornadiene with amines, providing a series of chiral ring-opened products in high yields (up to 97%) and with high enantioselectivities (>99%).The reaction can be performed at rt to obtain the desired product with high enantioselectivity.

AB - A new tunable chiral monophosphine was used as a ligand for asymmetric rhodium-catalyzed ring-opening of oxabenzonorbornadiene with amines, providing a series of chiral ring-opened products in high yields (up to 97%) and with high enantioselectivities (>99%).The reaction can be performed at rt to obtain the desired product with high enantioselectivity.

UR - https://www.scopus.com/pages/publications/84901022344

U2 - 10.1016/j.tetasy.2014.03.017

DO - 10.1016/j.tetasy.2014.03.017

M3 - Journal article

AN - SCOPUS:84901022344

SN - 0957-4166

VL - 25

SP - 709

EP - 717

JO - Tetrahedron Asymmetry

JF - Tetrahedron Asymmetry

IS - 9

ER -

Tunable chiral monophosphines as ligands in enantioselective rhodium-catalyzed ring-opening of oxabenzonorbornadienes with amines

Abstract

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