@article{fa7b9ac452674ddcbdf570e68b6ca854,
title = "Trans-[OsIII(salen)(CN)2]-: A new paramagnetic building block for the construction of molecule-based magnetic materials",
abstract = "A novel dicyanoosmium(III) complex, trans-Ph4P[Os III(salen)(CN)2]* CH2Cl2 * H2O (1; Ph4 P+ = tetraphenylphosphonium cation, salen2-=N, N′-ethylenebis(salicylideneaminato) dianion), has been synthesized and structurally characterized. Reactions of 1 with [Cu(Me3tacn)(H2O)2](ClO4) 2 (Me3tacn=1, 4, 7-trimethyl-1, 4, 7-triazacyclononane) under different conditions produce the 1-D ferromagnetic zigzag chains [Os(salen)(CN)2]2[Cu(Me3tacn)] * CH 3OH (2) and [Os(salen)(CN)2][Cu(Me3tacn)] * ClO4 (3).",
author = "Guo, \{Jun Fang\} and Yeung, \{Wai Fun\} and Lau, \{Pui Ha\} and Wang, \{Xiu Teng\} and Song Gao and Wong, \{Wing Tak\} and Chui, \{Stephen Sin Yin\} and Che, \{Chi Ming\} and Wong, \{Wai Yeung\} and Lau, \{Tai Chu\}",
note = "The work described in this paper was supported by grants from the National Natural Science Foundation of China (NSFC20831160505), the National Basic Research Program of China (2009CB929403), the Research Grants Council of Hong Kong Joint Research Scheme (N\_CityU 107/08), and the City University of Hong Kong (SRG 7002319). ",
year = "2010",
month = feb,
day = "15",
doi = "10.1021/ic9020178",
language = "English",
volume = "49",
pages = "1607--1614",
journal = "Inorganic Chemistry",
issn = "0020-1669",
publisher = "American Chemical Society",
number = "4",
}