Trans-[OsIII(salen)(CN)2]-: A new paramagnetic building block for the construction of molecule-based magnetic materials

Jun Fang Guo; Wai Fun Yeung; Pui Ha Lau; Xiu Teng Wang; Song Gao; Wing Tak Wong; Stephen Sin Yin Chui; Chi Ming Che; Wai Yeung Wong; Tai Chu Lau

doi:10.1021/ic9020178

Trans-[Os^III(salen)(CN)₂]^-: A new paramagnetic building block for the construction of molecule-based magnetic materials

Jun Fang Guo, Wai Fun Yeung, Pui Ha Lau, Xiu Teng Wang, Song Gao, Wing Tak Wong, Stephen Sin Yin Chui, Chi Ming Che, Wai Yeung Wong, Tai Chu Lau^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

28 Citations (Scopus)

Abstract

A novel dicyanoosmium(III) complex, trans-Ph₄P[Os ^III(salen)(CN)₂]* CH₂Cl₂ * H₂O (1; Ph₄ P⁺ = tetraphenylphosphonium cation, salen^2-=N, N′-ethylenebis(salicylideneaminato) dianion), has been synthesized and structurally characterized. Reactions of 1 with [Cu(Me₃tacn)(H₂O)₂](ClO₄) ₂ (Me₃tacn=1, 4, 7-trimethyl-1, 4, 7-triazacyclononane) under different conditions produce the 1-D ferromagnetic zigzag chains [Os(salen)(CN)₂]₂[Cu(Me₃tacn)] * CH ₃OH (2) and [Os(salen)(CN)₂][Cu(Me₃tacn)] * ClO₄ (3).

Original language	English
Pages (from-to)	1607-1614
Number of pages	8
Journal	Inorganic Chemistry
Volume	49
Issue number	4
DOIs	https://doi.org/10.1021/ic9020178
Publication status	Published - 15 Feb 2010

Scopus Subject Areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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@article{fa7b9ac452674ddcbdf570e68b6ca854,

title = "Trans-[OsIII(salen)(CN)2]-: A new paramagnetic building block for the construction of molecule-based magnetic materials",

abstract = "A novel dicyanoosmium(III) complex, trans-Ph4P[Os III(salen)(CN)2]* CH2Cl2 * H2O (1; Ph4 P+ = tetraphenylphosphonium cation, salen2-=N, N′-ethylenebis(salicylideneaminato) dianion), has been synthesized and structurally characterized. Reactions of 1 with [Cu(Me3tacn)(H2O)2](ClO4) 2 (Me3tacn=1, 4, 7-trimethyl-1, 4, 7-triazacyclononane) under different conditions produce the 1-D ferromagnetic zigzag chains [Os(salen)(CN)2]2[Cu(Me3tacn)] * CH 3OH (2) and [Os(salen)(CN)2][Cu(Me3tacn)] * ClO4 (3).",

author = "Guo, {Jun Fang} and Yeung, {Wai Fun} and Lau, {Pui Ha} and Wang, {Xiu Teng} and Song Gao and Wong, {Wing Tak} and Chui, {Stephen Sin Yin} and Che, {Chi Ming} and Wong, {Wai Yeung} and Lau, {Tai Chu}",

note = "The work described in this paper was supported by grants from the National Natural Science Foundation of China (NSFC20831160505), the National Basic Research Program of China (2009CB929403), the Research Grants Council of Hong Kong Joint Research Scheme (N_CityU 107/08), and the City University of Hong Kong (SRG 7002319). ",

year = "2010",

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day = "15",

doi = "10.1021/ic9020178",

language = "English",

volume = "49",

pages = "1607--1614",

journal = "Inorganic Chemistry",

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publisher = "American Chemical Society",

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T1 - Trans-[OsIII(salen)(CN)2]-

T2 - A new paramagnetic building block for the construction of molecule-based magnetic materials

AU - Guo, Jun Fang

AU - Yeung, Wai Fun

AU - Lau, Pui Ha

AU - Wang, Xiu Teng

AU - Gao, Song

AU - Wong, Wing Tak

AU - Chui, Stephen Sin Yin

AU - Che, Chi Ming

AU - Wong, Wai Yeung

AU - Lau, Tai Chu

N1 - The work described in this paper was supported by grants from the National Natural Science Foundation of China (NSFC20831160505), the National Basic Research Program of China (2009CB929403), the Research Grants Council of Hong Kong Joint Research Scheme (N_CityU 107/08), and the City University of Hong Kong (SRG 7002319).

PY - 2010/2/15

Y1 - 2010/2/15

N2 - A novel dicyanoosmium(III) complex, trans-Ph4P[Os III(salen)(CN)2]* CH2Cl2 * H2O (1; Ph4 P+ = tetraphenylphosphonium cation, salen2-=N, N′-ethylenebis(salicylideneaminato) dianion), has been synthesized and structurally characterized. Reactions of 1 with [Cu(Me3tacn)(H2O)2](ClO4) 2 (Me3tacn=1, 4, 7-trimethyl-1, 4, 7-triazacyclononane) under different conditions produce the 1-D ferromagnetic zigzag chains [Os(salen)(CN)2]2[Cu(Me3tacn)] * CH 3OH (2) and [Os(salen)(CN)2][Cu(Me3tacn)] * ClO4 (3).

AB - A novel dicyanoosmium(III) complex, trans-Ph4P[Os III(salen)(CN)2]* CH2Cl2 * H2O (1; Ph4 P+ = tetraphenylphosphonium cation, salen2-=N, N′-ethylenebis(salicylideneaminato) dianion), has been synthesized and structurally characterized. Reactions of 1 with [Cu(Me3tacn)(H2O)2](ClO4) 2 (Me3tacn=1, 4, 7-trimethyl-1, 4, 7-triazacyclononane) under different conditions produce the 1-D ferromagnetic zigzag chains [Os(salen)(CN)2]2[Cu(Me3tacn)] * CH 3OH (2) and [Os(salen)(CN)2][Cu(Me3tacn)] * ClO4 (3).

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SN - 0020-1669

VL - 49

SP - 1607

EP - 1614

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 4

ER -

Trans-[Os^III(salen)(CN)₂]^-: A new paramagnetic building block for the construction of molecule-based magnetic materials

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