The Crystal and Molecular Structure of catena-{Aquabis[2-methyl-2-(phenylthio)- propanoato]cadmium(II) monohydrate}

Graham Smith; Eric J. O’Reilly; Colin H.L. Kennard; Thomas C.W. Mak; Wai Hing Yip; Wing Hong Chan

doi:10.1071/CH9881769

The Crystal and Molecular Structure of catena-{Aquabis[2-methyl-2-(phenylthio)- propanoato]cadmium(II) monohydrate}

Graham Smith^*, Eric J. O’Reilly, Colin H.L. Kennard, Thomas C.W. Mak, Wai Hing Yip, Wing Hong Chan

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

9 Citations (Scopus)

Abstract

The crystal structure of the cadmium complex of 2-methyl-2-(phenylthio)propanoic acid, [Cd(C₆H₅SC(CH₃)₂CO₂)₂(H₂O)]. H₂O has been determined by X-ray diffration and refined to a residual R 0• 051 for 2725 observed reflections. Crystals are orthorhombic, space group P bca with a 10• 819(2), b 9• 030(1), c 47• 24(2) Å and Z 8. The stereochemistry about cadmium is distorted MO₆S seven-coordinate with Cd-S 2• 747(2) Å and a Cd-O range 2• 277-2• 491(5) Å. Bonds are from cadmium to a water, and to four oxygens from two bidentate carboxylate groups, one of which also forms a polymer link. The same carboxylate group is also involved in a five-membered (S, O) chelate ring.

Original language	English
Pages (from-to)	1769-1772
Number of pages	4
Journal	Australian Journal of Chemistry
Volume	41
Issue number	11
DOIs	https://doi.org/10.1071/CH9881769
Publication status	Published - 1988

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title = "The Crystal and Molecular Structure of catena-{Aquabis[2-methyl-2-(phenylthio)- propanoato]cadmium(II) monohydrate}",

abstract = "The crystal structure of the cadmium complex of 2-methyl-2-(phenylthio)propanoic acid, [Cd(C6H5SC(CH3)2CO2)2(H2O)]. H2O has been determined by X-ray diffration and refined to a residual R 0• 051 for 2725 observed reflections. Crystals are orthorhombic, space group P bca with a 10• 819(2), b 9• 030(1), c 47• 24(2) {\AA} and Z 8. The stereochemistry about cadmium is distorted MO6S seven-coordinate with Cd-S 2• 747(2) {\AA} and a Cd-O range 2• 277-2• 491(5) {\AA}. Bonds are from cadmium to a water, and to four oxygens from two bidentate carboxylate groups, one of which also forms a polymer link. The same carboxylate group is also involved in a five-membered (S, O) chelate ring.",

author = "Graham Smith and O{\textquoteright}Reilly, {Eric J.} and Kennard, {Colin H.L.} and Mak, {Thomas C.W.} and Yip, {Wai Hing} and Chan, {Wing Hong}",

year = "1988",

doi = "10.1071/CH9881769",

language = "English",

volume = "41",

pages = "1769--1772",

journal = "Australian Journal of Chemistry",

issn = "0004-9425",

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AU - Smith, Graham

AU - O’Reilly, Eric J.

AU - Kennard, Colin H.L.

AU - Mak, Thomas C.W.

AU - Yip, Wai Hing

AU - Chan, Wing Hong

PY - 1988

Y1 - 1988

N2 - The crystal structure of the cadmium complex of 2-methyl-2-(phenylthio)propanoic acid, [Cd(C6H5SC(CH3)2CO2)2(H2O)]. H2O has been determined by X-ray diffration and refined to a residual R 0• 051 for 2725 observed reflections. Crystals are orthorhombic, space group P bca with a 10• 819(2), b 9• 030(1), c 47• 24(2) Å and Z 8. The stereochemistry about cadmium is distorted MO6S seven-coordinate with Cd-S 2• 747(2) Å and a Cd-O range 2• 277-2• 491(5) Å. Bonds are from cadmium to a water, and to four oxygens from two bidentate carboxylate groups, one of which also forms a polymer link. The same carboxylate group is also involved in a five-membered (S, O) chelate ring.

AB - The crystal structure of the cadmium complex of 2-methyl-2-(phenylthio)propanoic acid, [Cd(C6H5SC(CH3)2CO2)2(H2O)]. H2O has been determined by X-ray diffration and refined to a residual R 0• 051 for 2725 observed reflections. Crystals are orthorhombic, space group P bca with a 10• 819(2), b 9• 030(1), c 47• 24(2) Å and Z 8. The stereochemistry about cadmium is distorted MO6S seven-coordinate with Cd-S 2• 747(2) Å and a Cd-O range 2• 277-2• 491(5) Å. Bonds are from cadmium to a water, and to four oxygens from two bidentate carboxylate groups, one of which also forms a polymer link. The same carboxylate group is also involved in a five-membered (S, O) chelate ring.

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SN - 0004-9425

VL - 41

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JF - Australian Journal of Chemistry

IS - 11

ER -

The Crystal and Molecular Structure of catena-{Aquabis[2-methyl-2-(phenylthio)- propanoato]cadmium(II) monohydrate}

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