TY - JOUR
T1 - Tb(III) postsynthetic functional coordination polymer coatings on ZnO micronanoarrays and their application in small molecule sensing
AU - Wang, Yi
AU - Zhang, Feng
AU - Fang, Zhengsong
AU - Yu, Minghao
AU - Yang, Yangyi
AU - Wong, Ka Leung
N1 - Funding Information:
The authors acknowledge the financial support of the National Natural Science Foundation of China (51472275, 20973203 and 91022012) and Guangdong Natural Science Foundation (2014A030313207).
PY - 2016
Y1 - 2016
N2 - A series of luminescent coatings of Tb3+ functionalized coordination polymers (CPs) consolidated by different multi-carboxylic ligands [1,4-benzenedicarboxylate, 1,3,5-benzenetricarboxylate, 2,6-naphthalenedicarboxylate] are fabricated on ZnO micronanoarrays. These hybrid luminescent coatings of Tb(iii)@CPs/ZnO (Tb(iii) functionalized CP/ZnO) are prepared by solvothermal synthesis and a postsynthetic functionalization (PSF) approach. Tb(iii)@MOF-5/ZnO exhibits a highly detectable luminescence response for acetone molecules, and its structure, composition and morphology are characterized by XRD, EDS, ICP and SEM, respectively. It is first demonstrated that a lanthanide ion functionalized hybrid micronano-CP/ZnO coating is used as a small molecule sensor successfully.
AB - A series of luminescent coatings of Tb3+ functionalized coordination polymers (CPs) consolidated by different multi-carboxylic ligands [1,4-benzenedicarboxylate, 1,3,5-benzenetricarboxylate, 2,6-naphthalenedicarboxylate] are fabricated on ZnO micronanoarrays. These hybrid luminescent coatings of Tb(iii)@CPs/ZnO (Tb(iii) functionalized CP/ZnO) are prepared by solvothermal synthesis and a postsynthetic functionalization (PSF) approach. Tb(iii)@MOF-5/ZnO exhibits a highly detectable luminescence response for acetone molecules, and its structure, composition and morphology are characterized by XRD, EDS, ICP and SEM, respectively. It is first demonstrated that a lanthanide ion functionalized hybrid micronano-CP/ZnO coating is used as a small molecule sensor successfully.
UR - http://www.scopus.com/inward/record.url?scp=84988422827&partnerID=8YFLogxK
U2 - 10.1039/c6tc01511e
DO - 10.1039/c6tc01511e
M3 - Journal article
AN - SCOPUS:84988422827
SN - 2050-7526
VL - 4
SP - 8466
EP - 8472
JO - Journal of Materials Chemistry C
JF - Journal of Materials Chemistry C
IS - 36
ER -