Synthesis, structures and photoluminescence behavior of some group 10 metal alkynyl complexes derived from 3-(N-carbazolyl)-1-propyne

Cheuk Lam Ho; Wai Yeung Wong

doi:10.1016/j.jorganchem.2005.09.006

Synthesis, structures and photoluminescence behavior of some group 10 metal alkynyl complexes derived from 3-(N-carbazolyl)-1-propyne

Cheuk Lam Ho, Wai Yeung Wong^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

19 Citations (Scopus)

Abstract

A new class of luminescent and thermally stable mononuclear group 10 platinum(II) and palladium(II) acetylides trans-[Pt(PR₃) ₂(L)₂] (R = Bu, Et) and trans-[Pd(PBu₃) ₂(L)₂] (LH = 3-(N-carbazolyl)-1-propyne) have been successfully synthesized and characterized. The structural properties of these discrete metal complexes have been studied by X-ray crystallography. We report their optical absorption and photoluminescence spectra and interpret the results in terms of the nature of the metal center and the type of phosphines used. Our investigations indicate that they display heavy metal-enhanced phosphorescence bands at 77 K and we find that the platinum complexes afford more intense triplet emission than that for the palladium congener, consistent with the stronger heavy-atom effect of the third row element than the second row neighbor of the same group.

Original language	English
Pages (from-to)	395-402
Number of pages	8
Journal	Journal of Organometallic Chemistry
Volume	691
Issue number	3
DOIs	https://doi.org/10.1016/j.jorganchem.2005.09.006
Publication status	Published - 15 Jan 2006

Scopus Subject Areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

User-Defined Keywords

Alkynyl complexes
Carbazole
Palladium
Photoluminescence
Platinum

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10.1016/j.jorganchem.2005.09.006

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title = "Synthesis, structures and photoluminescence behavior of some group 10 metal alkynyl complexes derived from 3-(N-carbazolyl)-1-propyne",

abstract = "A new class of luminescent and thermally stable mononuclear group 10 platinum(II) and palladium(II) acetylides trans-[Pt(PR3) 2(L)2] (R = Bu, Et) and trans-[Pd(PBu3) 2(L)2] (LH = 3-(N-carbazolyl)-1-propyne) have been successfully synthesized and characterized. The structural properties of these discrete metal complexes have been studied by X-ray crystallography. We report their optical absorption and photoluminescence spectra and interpret the results in terms of the nature of the metal center and the type of phosphines used. Our investigations indicate that they display heavy metal-enhanced phosphorescence bands at 77 K and we find that the platinum complexes afford more intense triplet emission than that for the palladium congener, consistent with the stronger heavy-atom effect of the third row element than the second row neighbor of the same group.",

keywords = "Alkynyl complexes, Carbazole, Palladium, Photoluminescence, Platinum",

author = "Ho, {Cheuk Lam} and Wong, {Wai Yeung}",

note = "Funding Information: Financial support from a CERG Grant from the Hong Kong Research Grants Council of the Hong Kong SAR, P.R. China (Project No. HKBU2022/03P) is gratefully acknowledged.",

year = "2006",

month = jan,

day = "15",

doi = "10.1016/j.jorganchem.2005.09.006",

language = "English",

volume = "691",

pages = "395--402",

journal = "Journal of Organometallic Chemistry",

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number = "3",

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TY - JOUR

T1 - Synthesis, structures and photoluminescence behavior of some group 10 metal alkynyl complexes derived from 3-(N-carbazolyl)-1-propyne

AU - Ho, Cheuk Lam

AU - Wong, Wai Yeung

N1 - Funding Information: Financial support from a CERG Grant from the Hong Kong Research Grants Council of the Hong Kong SAR, P.R. China (Project No. HKBU2022/03P) is gratefully acknowledged.

PY - 2006/1/15

Y1 - 2006/1/15

N2 - A new class of luminescent and thermally stable mononuclear group 10 platinum(II) and palladium(II) acetylides trans-[Pt(PR3) 2(L)2] (R = Bu, Et) and trans-[Pd(PBu3) 2(L)2] (LH = 3-(N-carbazolyl)-1-propyne) have been successfully synthesized and characterized. The structural properties of these discrete metal complexes have been studied by X-ray crystallography. We report their optical absorption and photoluminescence spectra and interpret the results in terms of the nature of the metal center and the type of phosphines used. Our investigations indicate that they display heavy metal-enhanced phosphorescence bands at 77 K and we find that the platinum complexes afford more intense triplet emission than that for the palladium congener, consistent with the stronger heavy-atom effect of the third row element than the second row neighbor of the same group.

AB - A new class of luminescent and thermally stable mononuclear group 10 platinum(II) and palladium(II) acetylides trans-[Pt(PR3) 2(L)2] (R = Bu, Et) and trans-[Pd(PBu3) 2(L)2] (LH = 3-(N-carbazolyl)-1-propyne) have been successfully synthesized and characterized. The structural properties of these discrete metal complexes have been studied by X-ray crystallography. We report their optical absorption and photoluminescence spectra and interpret the results in terms of the nature of the metal center and the type of phosphines used. Our investigations indicate that they display heavy metal-enhanced phosphorescence bands at 77 K and we find that the platinum complexes afford more intense triplet emission than that for the palladium congener, consistent with the stronger heavy-atom effect of the third row element than the second row neighbor of the same group.

KW - Alkynyl complexes

KW - Carbazole

KW - Palladium

KW - Photoluminescence

KW - Platinum

UR - http://www.scopus.com/inward/record.url?scp=29344463830&partnerID=8YFLogxK

U2 - 10.1016/j.jorganchem.2005.09.006

DO - 10.1016/j.jorganchem.2005.09.006

M3 - Journal article

AN - SCOPUS:29344463830

SN - 0022-328X

VL - 691

SP - 395

EP - 402

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 3

ER -

Synthesis, structures and photoluminescence behavior of some group 10 metal alkynyl complexes derived from 3-(N-carbazolyl)-1-propyne

Abstract

Scopus Subject Areas

User-Defined Keywords

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