Synthesis, structure and preliminary complexation behaviour of macrocyclic thioureas and ureas

Mark Rosser; David Parker; George Ferguson; John F. Gallagher; Judith A.K. Howard; Dmitri S. Yufit

doi:10.1039/C39930001267

Synthesis, structure and preliminary complexation behaviour of macrocyclic thioureas and ureas

Mark Rosser
, David Parker^*
, George Ferguson
, John F. Gallagher
, Judith A.K. Howard
, Dmitri S. Yufit

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

17 Citations (Scopus)

Abstract

Tricyclic ligands incorporating bis(thiourea) subunits may be prepared from the corresponding monocyclic [18]- and [24]-ring N₄O₂ and N₄O₄ polyaza-compounds and adopt a trans-conformation in the free ligand; an unusual trisilver(I) complex is formed with the N ₄O₂-derived ligand with bridging nitrate groups in which the thiourea groups are cis-oriented.

Original language	English
Pages (from-to)	1267-1269
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	16
DOIs	https://doi.org/10.1039/C39930001267
Publication status	Published - Aug 1993

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10.1039/C39930001267

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title = "Synthesis, structure and preliminary complexation behaviour of macrocyclic thioureas and ureas",

abstract = "Tricyclic ligands incorporating bis(thiourea) subunits may be prepared from the corresponding monocyclic [18]- and [24]-ring N4O2 and N4O4 polyaza-compounds and adopt a trans-conformation in the free ligand; an unusual trisilver(I) complex is formed with the N 4O2-derived ligand with bridging nitrate groups in which the thiourea groups are cis-oriented.",

author = "Mark Rosser and David Parker and George Ferguson and Gallagher, \{John F.\} and Howard, \{Judith A.K.\} and Yufit, \{Dmitri S.\}",

year = "1993",

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doi = "10.1039/C39930001267",

language = "English",

pages = "1267--1269",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

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T1 - Synthesis, structure and preliminary complexation behaviour of macrocyclic thioureas and ureas

AU - Rosser, Mark

AU - Parker, David

AU - Ferguson, George

AU - Gallagher, John F.

AU - Howard, Judith A.K.

AU - Yufit, Dmitri S.

PY - 1993/8

Y1 - 1993/8

N2 - Tricyclic ligands incorporating bis(thiourea) subunits may be prepared from the corresponding monocyclic [18]- and [24]-ring N4O2 and N4O4 polyaza-compounds and adopt a trans-conformation in the free ligand; an unusual trisilver(I) complex is formed with the N 4O2-derived ligand with bridging nitrate groups in which the thiourea groups are cis-oriented.

AB - Tricyclic ligands incorporating bis(thiourea) subunits may be prepared from the corresponding monocyclic [18]- and [24]-ring N4O2 and N4O4 polyaza-compounds and adopt a trans-conformation in the free ligand; an unusual trisilver(I) complex is formed with the N 4O2-derived ligand with bridging nitrate groups in which the thiourea groups are cis-oriented.

UR - https://www.scopus.com/pages/publications/0141548158

U2 - 10.1039/C39930001267

DO - 10.1039/C39930001267

M3 - Journal article

AN - SCOPUS:0141548158

SN - 0022-4936

SP - 1267

EP - 1269

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 16

ER -

Synthesis, structure and preliminary complexation behaviour of macrocyclic thioureas and ureas

Abstract

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