Synthesis, structure and near-infrared luminescence of neutral 3d–4f bi-metallic monoporphyrinate complexes

Rick Wai Kwok Wong; Anxin Hou; Jianping Guo; Hongshan He; Lilu Zhang; Wai Yeung Wong; King Fai Li; Kok Wai Cheah; F. Xue; Thomas C.W. Mak

doi:10.1039/B104993N

Synthesis, structure and near-infrared luminescence of neutral 3d–4f bi-metallic monoporphyrinate complexes

Rick Wai Kwok Wong^*
, Anxin Hou
, Jianping Guo
, Hongshan He
, Lilu Zhang
, Wai Yeung Wong
, King Fai Li
, Kok Wai Cheah
, F. Xue
, Thomas C.W. Mak

^*Corresponding author for this work

Research output: Contribution to journal › Journal article › peer-review

89 Citations (Scopus)

Abstract

The interaction of cationic lanthanide complexes [Ln(porp)(H₂O)₃]⁺ (Ln = Er or Yb; porp = porphyrinate) with sodium (cyclopentadienyl)tris(diethylphosphito)cobaltate (NaL_OEt) gives the neutral 3d-4f bi-metallic porphyrinate complexes, [(L_OEt)Ln(porp)]. X-Ray structural analyses reveal that these complexes are seven-coordinate with the three oxygen atoms of the O₃-tripodal ligand, L_OEt, coordinated to the lanthanide metal behaving as a 6-electron donor. Photophysical measurements show that the porphyrinate ligand behaves as a sensitizer by absorbing visible light to excite the Ln(III) metal ions, producing near-infrared emission.

Original language	English
Pages (from-to)	3092-3098
Number of pages	7
Journal	Journal of the Chemical Society - Dalton Transactions
Issue number	20
DOIs	https://doi.org/10.1039/B104993N
Publication status	Published - 27 Sept 2001

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@article{94b057ecf2124e0d8c5c831032149ef9,

title = "Synthesis, structure and near-infrared luminescence of neutral 3d–4f bi-metallic monoporphyrinate complexes",

abstract = "The interaction of cationic lanthanide complexes [Ln(porp)(H2O)3]+ (Ln = Er or Yb; porp = porphyrinate) with sodium (cyclopentadienyl)tris(diethylphosphito)cobaltate (NaLOEt) gives the neutral 3d-4f bi-metallic porphyrinate complexes, [(LOEt)Ln(porp)]. X-Ray structural analyses reveal that these complexes are seven-coordinate with the three oxygen atoms of the O3-tripodal ligand, LOEt, coordinated to the lanthanide metal behaving as a 6-electron donor. Photophysical measurements show that the porphyrinate ligand behaves as a sensitizer by absorbing visible light to excite the Ln(III) metal ions, producing near-infrared emission.",

author = "Wong, \{Rick Wai Kwok\} and Anxin Hou and Jianping Guo and Hongshan He and Lilu Zhang and Wong, \{Wai Yeung\} and Li, \{King Fai\} and Cheah, \{Kok Wai\} and F. Xue and Mak, \{Thomas C.W.\}",

year = "2001",

month = sep,

day = "27",

doi = "10.1039/B104993N",

language = "English",

pages = "3092--3098",

journal = " Journal of the Chemical Society - Dalton Transactions",

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number = "20",

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TY - JOUR

T1 - Synthesis, structure and near-infrared luminescence of neutral 3d–4f bi-metallic monoporphyrinate complexes

AU - Wong, Rick Wai Kwok

AU - Hou, Anxin

AU - Guo, Jianping

AU - He, Hongshan

AU - Zhang, Lilu

AU - Wong, Wai Yeung

AU - Li, King Fai

AU - Cheah, Kok Wai

AU - Xue, F.

AU - Mak, Thomas C.W.

PY - 2001/9/27

Y1 - 2001/9/27

N2 - The interaction of cationic lanthanide complexes [Ln(porp)(H2O)3]+ (Ln = Er or Yb; porp = porphyrinate) with sodium (cyclopentadienyl)tris(diethylphosphito)cobaltate (NaLOEt) gives the neutral 3d-4f bi-metallic porphyrinate complexes, [(LOEt)Ln(porp)]. X-Ray structural analyses reveal that these complexes are seven-coordinate with the three oxygen atoms of the O3-tripodal ligand, LOEt, coordinated to the lanthanide metal behaving as a 6-electron donor. Photophysical measurements show that the porphyrinate ligand behaves as a sensitizer by absorbing visible light to excite the Ln(III) metal ions, producing near-infrared emission.

AB - The interaction of cationic lanthanide complexes [Ln(porp)(H2O)3]+ (Ln = Er or Yb; porp = porphyrinate) with sodium (cyclopentadienyl)tris(diethylphosphito)cobaltate (NaLOEt) gives the neutral 3d-4f bi-metallic porphyrinate complexes, [(LOEt)Ln(porp)]. X-Ray structural analyses reveal that these complexes are seven-coordinate with the three oxygen atoms of the O3-tripodal ligand, LOEt, coordinated to the lanthanide metal behaving as a 6-electron donor. Photophysical measurements show that the porphyrinate ligand behaves as a sensitizer by absorbing visible light to excite the Ln(III) metal ions, producing near-infrared emission.

UR - https://pubs.rsc.org/en/content/articlelanding/2001/dt/b104993n

UR - https://www.scopus.com/pages/publications/0034740333

U2 - 10.1039/B104993N

DO - 10.1039/B104993N

M3 - Journal article

AN - SCOPUS:0034740333

SN - 0300-9246

SP - 3092

EP - 3098

JO - Journal of the Chemical Society - Dalton Transactions

JF - Journal of the Chemical Society - Dalton Transactions

IS - 20

ER -

Synthesis, structure and near-infrared luminescence of neutral 3d–4f bi-metallic monoporphyrinate complexes

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