Synthesis, solution dynamics and x-ray crystal structures of neodymium-ylide complexes, [(C5H4R)3NdCH2P(Me)Ph2] (R = H, But)

Wai Kwok Wong; Jingwen Guan; Qi Shen; Lilu Zhang; Yongua Lin; Wing Tak Wong

doi:10.1016/0277-5387(94)00177-G

Synthesis, solution dynamics and x-ray crystal structures of neodymium-ylide complexes, [(C₅H₄R)₃NdCH₂P(Me)Ph₂] (R = H, Bu^t)

Wai Kwok Wong^*
, Jingwen Guan
, Qi Shen
, Lilu Zhang
, Yongua Lin
, Wing Tak Wong

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

10 Citations (Scopus)

Abstract

The interaction of [(C₅H₄R)₂NdCl·2LiCl] (R = H, Bu^t) with one equivalent of Li[(CH₂(CH₂PPh₂] in refluxing tetrahydrofuran gave the purplish-blue complex [(C₅H₄R)₃NdCH₂P(Me)Ph₂] in 50% yield. The compounds have been carefully characterized by analytical, spectroscopic and X-ray diffraction methods. Variable temperature ³¹P{¹H} NMR spectroscopy indicated the existence of the following equilibrium: [(C₅H₄R)₃NdCH₂P(Me)Ph₂] + THF ⇌ (C₅H₄R)₃Nd(THF)+CH₂P(Me)Ph₂. At room temperature, the exchange between the coordinated and free ylide ligand is slow on the NMR time scale.

Original language	English
Pages (from-to)	277-283
Number of pages	7
Journal	Polyhedron
Volume	14
Issue number	2
DOIs	https://doi.org/10.1016/0277-5387(94)00177-G
Publication status	Published - Jan 1995

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@article{68aa95224fcb48d2afb8f3e865a12366,

title = "Synthesis, solution dynamics and x-ray crystal structures of neodymium-ylide complexes, [(C5H4R)3NdCH2P(Me)Ph2] (R = H, But)",

abstract = "The interaction of [(C5H4R)2NdCl·2LiCl] (R = H, But) with one equivalent of Li[(CH2(CH2PPh2] in refluxing tetrahydrofuran gave the purplish-blue complex [(C5H4R)3NdCH2P(Me)Ph2] in 50\% yield. The compounds have been carefully characterized by analytical, spectroscopic and X-ray diffraction methods. Variable temperature 31P\{1H\} NMR spectroscopy indicated the existence of the following equilibrium: [(C5H4R)3NdCH2P(Me)Ph2] + THF ⇌ (C5H4R)3Nd(THF)+CH2P(Me)Ph2. At room temperature, the exchange between the coordinated and free ylide ligand is slow on the NMR time scale.",

author = "Wong, \{Wai Kwok\} and Jingwen Guan and Qi Shen and Lilu Zhang and Yongua Lin and Wong, \{Wing Tak\}",

note = "Funding Information: Acknowledgements--W.-K. Wong thanks the Hong Kong BaptistC ollege,t heHong Kong ResearchG rant Councila ndt heC roucheFr oundationfo r financiasl up-port. W.-T. Wong thankst he Hong Kong Research Grant Council and the Universityo f Hong Kong for financiasl upport.",

year = "1995",

month = jan,

doi = "10.1016/0277-5387(94)00177-G",

language = "English",

volume = "14",

pages = "277--283",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier Ltd.",

number = "2",

}

TY - JOUR

T1 - Synthesis, solution dynamics and x-ray crystal structures of neodymium-ylide complexes, [(C5H4R)3NdCH2P(Me)Ph2] (R = H, But)

AU - Wong, Wai Kwok

AU - Guan, Jingwen

AU - Shen, Qi

AU - Zhang, Lilu

AU - Lin, Yongua

AU - Wong, Wing Tak

N1 - Funding Information: Acknowledgements--W.-K. Wong thanks the Hong Kong BaptistC ollege,t heHong Kong ResearchG rant Councila ndt heC roucheFr oundationfo r financiasl up-port. W.-T. Wong thankst he Hong Kong Research Grant Council and the Universityo f Hong Kong for financiasl upport.

PY - 1995/1

Y1 - 1995/1

N2 - The interaction of [(C5H4R)2NdCl·2LiCl] (R = H, But) with one equivalent of Li[(CH2(CH2PPh2] in refluxing tetrahydrofuran gave the purplish-blue complex [(C5H4R)3NdCH2P(Me)Ph2] in 50% yield. The compounds have been carefully characterized by analytical, spectroscopic and X-ray diffraction methods. Variable temperature 31P{1H} NMR spectroscopy indicated the existence of the following equilibrium: [(C5H4R)3NdCH2P(Me)Ph2] + THF ⇌ (C5H4R)3Nd(THF)+CH2P(Me)Ph2. At room temperature, the exchange between the coordinated and free ylide ligand is slow on the NMR time scale.

AB - The interaction of [(C5H4R)2NdCl·2LiCl] (R = H, But) with one equivalent of Li[(CH2(CH2PPh2] in refluxing tetrahydrofuran gave the purplish-blue complex [(C5H4R)3NdCH2P(Me)Ph2] in 50% yield. The compounds have been carefully characterized by analytical, spectroscopic and X-ray diffraction methods. Variable temperature 31P{1H} NMR spectroscopy indicated the existence of the following equilibrium: [(C5H4R)3NdCH2P(Me)Ph2] + THF ⇌ (C5H4R)3Nd(THF)+CH2P(Me)Ph2. At room temperature, the exchange between the coordinated and free ylide ligand is slow on the NMR time scale.

UR - https://www.scopus.com/pages/publications/0041025046

U2 - 10.1016/0277-5387(94)00177-G

DO - 10.1016/0277-5387(94)00177-G

M3 - Journal article

AN - SCOPUS:0041025046

SN - 0277-5387

VL - 14

SP - 277

EP - 283

JO - Polyhedron

JF - Polyhedron

IS - 2

ER -

Synthesis, solution dynamics and x-ray crystal structures of neodymium-ylide complexes, [(C₅H₄R)₃NdCH₂P(Me)Ph₂] (R = H, Bu^t)

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