Synthesis of Unexpected trans-meso Macrocycle from Novel Unsymmetrical Tetraphenylene

Chun Lin Deng; Sam C.K. Hau; Xiao Shui Peng; Henry N.C. Wong

doi:10.1055/s-0035-1561480

Synthesis of Unexpected trans-meso Macrocycle from Novel Unsymmetrical Tetraphenylene

Chun Lin Deng, Sam C.K. Hau^*, Xiao Shui Peng, Henry N.C. Wong

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

8 Citations (Scopus)

Abstract

A highly unsymmetrical trisubstituted tetraphenylene was designed and synthesized as a novel superamolecular scaffold for an unexpected trans-meso tetraphenylene macrocycle, whose structure was unequivocally characterized by an X-ray crystallographic analysis. With the defined and electron-rich aromatic cavity, this macrocycle could be further modified to be a potential host for organic cations with biological interest.

Original language	English
Article number	st-2016-w0311-c
Pages (from-to)	2095-2100
Number of pages	6
Journal	Synlett
Volume	27
Issue number	14
DOIs	https://doi.org/10.1055/s-0035-1561480
Publication status	Published - 1 Sept 2016

User-Defined Keywords

cation π interactions
host-guest chemistry
macrocycle
nonplanar hydrocarbon
tetraphenylene

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10.1055/s-0035-1561480

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title = "Synthesis of Unexpected trans-meso Macrocycle from Novel Unsymmetrical Tetraphenylene",

abstract = "A highly unsymmetrical trisubstituted tetraphenylene was designed and synthesized as a novel superamolecular scaffold for an unexpected trans-meso tetraphenylene macrocycle, whose structure was unequivocally characterized by an X-ray crystallographic analysis. With the defined and electron-rich aromatic cavity, this macrocycle could be further modified to be a potential host for organic cations with biological interest.",

keywords = "cation π interactions, host-guest chemistry, macrocycle, nonplanar hydrocarbon, tetraphenylene",

author = "Deng, {Chun Lin} and Hau, {Sam C.K.} and Peng, {Xiao Shui} and Wong, {Henry N.C.}",

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AU - Deng, Chun Lin

AU - Hau, Sam C.K.

AU - Peng, Xiao Shui

AU - Wong, Henry N.C.

N1 - Publisher Copyright: © Georg Thieme Verlag Stuttgart - New York.

PY - 2016/9/1

Y1 - 2016/9/1

N2 - A highly unsymmetrical trisubstituted tetraphenylene was designed and synthesized as a novel superamolecular scaffold for an unexpected trans-meso tetraphenylene macrocycle, whose structure was unequivocally characterized by an X-ray crystallographic analysis. With the defined and electron-rich aromatic cavity, this macrocycle could be further modified to be a potential host for organic cations with biological interest.

AB - A highly unsymmetrical trisubstituted tetraphenylene was designed and synthesized as a novel superamolecular scaffold for an unexpected trans-meso tetraphenylene macrocycle, whose structure was unequivocally characterized by an X-ray crystallographic analysis. With the defined and electron-rich aromatic cavity, this macrocycle could be further modified to be a potential host for organic cations with biological interest.

KW - cation π interactions

KW - host-guest chemistry

KW - macrocycle

KW - nonplanar hydrocarbon

KW - tetraphenylene

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U2 - 10.1055/s-0035-1561480

DO - 10.1055/s-0035-1561480

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IS - 14

M1 - st-2016-w0311-c

ER -

Synthesis of Unexpected trans-meso Macrocycle from Novel Unsymmetrical Tetraphenylene

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