Synthesis of ruthenium (II) complexes containing a dihydroperimidine- derived phosphine ligand and their application in transfer hydrogenation of ketones

Qi Fu; Lei Zhang; Tao Yi; Mingjun Zou; Xiaoyan Wang; Haiyan Fu; Ruixiang Li; Hua Chen

doi:10.1016/j.inoche.2013.10.013

Synthesis of ruthenium (II) complexes containing a dihydroperimidine- derived phosphine ligand and their application in transfer hydrogenation of ketones

Qi Fu, Lei Zhang, Tao Yi, Mingjun Zou, Xiaoyan Wang, Haiyan Fu, Ruixiang Li^*, Hua Chen

^*Corresponding author for this work

Research output: Contribution to journal › Journal article › peer-review

15 Citations (Scopus)

Abstract

The new ruthenium (II) phosphine complexes (η⁶-C ₆H₆)RuCl₂[μ- (PPh₂CH ₂N)₂CH₂(C₁₀H₆)]RuCl ₂(η⁶-C₆H₆) (1) and RuCl ₂(PPh₃)[(PPh₂CH₂N) ₂CH₂(C₁₀H₆)] (2) were synthesized and characterized by ¹H NMR, ³¹P {¹H} NMR and elemental analysis. Moreover, the structure of ruthenium (II) phosphine complex 1 was confirmed by X-ray crystallography. With complex 1 as the catalyst, the transfer hydrogenation of ketones reacted well, affording the corresponding alcohols in good yields under mild conditions.

Original language	English
Pages (from-to)	28-32
Number of pages	5
Journal	Inorganic Chemistry Communications
Volume	38
DOIs	https://doi.org/10.1016/j.inoche.2013.10.013
Publication status	Published - Dec 2013

Scopus Subject Areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

User-Defined Keywords

Ketone
Phosphine
Ruthenium
Transfer hydrogenation

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10.1016/j.inoche.2013.10.013

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@article{61356a96bb1c4541b30b48379f8c6ceb,

title = "Synthesis of ruthenium (II) complexes containing a dihydroperimidine- derived phosphine ligand and their application in transfer hydrogenation of ketones",

abstract = "The new ruthenium (II) phosphine complexes (η6-C 6H6)RuCl2[μ- (PPh2CH 2N)2CH2(C10H6)]RuCl 2(η6-C6H6) (1) and RuCl 2(PPh3)[(PPh2CH2N) 2CH2(C10H6)] (2) were synthesized and characterized by 1H NMR, 31P {1H} NMR and elemental analysis. Moreover, the structure of ruthenium (II) phosphine complex 1 was confirmed by X-ray crystallography. With complex 1 as the catalyst, the transfer hydrogenation of ketones reacted well, affording the corresponding alcohols in good yields under mild conditions.",

keywords = "Ketone, Phosphine, Ruthenium, Transfer hydrogenation",

author = "Qi Fu and Lei Zhang and Tao Yi and Mingjun Zou and Xiaoyan Wang and Haiyan Fu and Ruixiang Li and Hua Chen",

note = "Funding Information: We are grateful for the financial support from the National Natural Science Foundation of China (nos 20371032 ).",

year = "2013",

month = dec,

doi = "10.1016/j.inoche.2013.10.013",

language = "English",

volume = "38",

pages = "28--32",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier BV",

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TY - JOUR

T1 - Synthesis of ruthenium (II) complexes containing a dihydroperimidine- derived phosphine ligand and their application in transfer hydrogenation of ketones

AU - Fu, Qi

AU - Zhang, Lei

AU - Yi, Tao

AU - Zou, Mingjun

AU - Wang, Xiaoyan

AU - Fu, Haiyan

AU - Li, Ruixiang

AU - Chen, Hua

N1 - Funding Information: We are grateful for the financial support from the National Natural Science Foundation of China (nos 20371032 ).

PY - 2013/12

Y1 - 2013/12

N2 - The new ruthenium (II) phosphine complexes (η6-C 6H6)RuCl2[μ- (PPh2CH 2N)2CH2(C10H6)]RuCl 2(η6-C6H6) (1) and RuCl 2(PPh3)[(PPh2CH2N) 2CH2(C10H6)] (2) were synthesized and characterized by 1H NMR, 31P {1H} NMR and elemental analysis. Moreover, the structure of ruthenium (II) phosphine complex 1 was confirmed by X-ray crystallography. With complex 1 as the catalyst, the transfer hydrogenation of ketones reacted well, affording the corresponding alcohols in good yields under mild conditions.

AB - The new ruthenium (II) phosphine complexes (η6-C 6H6)RuCl2[μ- (PPh2CH 2N)2CH2(C10H6)]RuCl 2(η6-C6H6) (1) and RuCl 2(PPh3)[(PPh2CH2N) 2CH2(C10H6)] (2) were synthesized and characterized by 1H NMR, 31P {1H} NMR and elemental analysis. Moreover, the structure of ruthenium (II) phosphine complex 1 was confirmed by X-ray crystallography. With complex 1 as the catalyst, the transfer hydrogenation of ketones reacted well, affording the corresponding alcohols in good yields under mild conditions.

KW - Ketone

KW - Phosphine

KW - Ruthenium

KW - Transfer hydrogenation

UR - http://www.scopus.com/inward/record.url?scp=84886744124&partnerID=8YFLogxK

U2 - 10.1016/j.inoche.2013.10.013

DO - 10.1016/j.inoche.2013.10.013

M3 - Journal article

AN - SCOPUS:84886744124

SN - 1387-7003

VL - 38

SP - 28

EP - 32

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

ER -

Synthesis of ruthenium (II) complexes containing a dihydroperimidine- derived phosphine ligand and their application in transfer hydrogenation of ketones

Abstract

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