Abstract
Novel diselenide-linked porphyrin dimers were synthesized under phase-transfer catalysis conditions. The targeted compounds were characterized by 1H-NMR, high-resolution mass spectrometry, UV/VIS and fluorescence spectroscopies, redox-potential measurements, and elemental analysis. The interaction of the title compounds with DNA was studied using UV/VIS, fluorescence, and circular dichroism (CD) spectroscopies. The relative rates of singlet-oxygen production from the diselenide-linked porphyrin dimers upon photoirradiation were also measured.
| Original language | English |
|---|---|
| Pages (from-to) | 1131-1143 |
| Number of pages | 13 |
| Journal | Chemistry and Biodiversity |
| Volume | 6 |
| Issue number | 7 |
| DOIs | |
| Publication status | Published - Jul 2009 |
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