Synthesis of new mer,trans-rhodium(III) hydrido-bis(acetylide) complexes: Structure of mer,trans-[(PMe3)3Rh(C{triple bond, long}C-C6H4-4-NMe2)2H]

Xunjin ZHU; Richard M. Ward; David Albesa-Jové; Judith A.K. Howard; Laurent Porrès; Andrew Beeby; Paul J. Low; Rick W K WONG; Todd B. Marder

doi:10.1016/j.ica.2005.11.030

Synthesis of new mer,trans-rhodium(III) hydrido-bis(acetylide) complexes: Structure of mer,trans-[(PMe₃)₃Rh(C{triple bond, long}C-C₆H₄-4-NMe₂)₂H]

Xunjin ZHU
, Richard M. Ward
, David Albesa-Jové
, Judith A.K. Howard
, Laurent Porrès
, Andrew Beeby
, Paul J. Low
, Rick W K WONG
, Todd B. Marder^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

11 Citations (Scopus)

Abstract

Terminal alkynes (R-C{triple bond, long}C-H, R = 1-naphthyl, 9-anthryl, 4-Me₂N-C₆H₄-, or the longer analogue, 4-(4-Me₂N-C₆H₄-C{triple bond, long}C-)-C₆H₄-) react with [Rh(PMe₃)₄Me] at ambient temperature, with loss of methane and one PMe₃ ligand, to form the corresponding mer,trans-[(PMe₃)₃Rh(C{triple bond, long}CR)₂H] compounds in excellent yield. In this preliminary study, the synthesis and spectroscopic characterization of the four new compounds are reported, along with the single-crystal structure of the R = 4-Me₂N-C₆H₄ derivative.

Original language	English
Pages (from-to)	2859-2863
Number of pages	5
Journal	Inorganica Chimica Acta
Volume	359
Issue number	9
DOIs	https://doi.org/10.1016/j.ica.2005.11.030
Publication status	Published - 1 Jun 2006

User-Defined Keywords

Acetylide
Alkynyl
Crystal structure
Hydride
Luminescent

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10.1016/j.ica.2005.11.030

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@article{ee470a4aa01f4410a37c67d3fb0ed52c,

title = "Synthesis of new mer,trans-rhodium(III) hydrido-bis(acetylide) complexes: Structure of mer,trans-[(PMe3)3Rh(C\{triple bond, long\}C-C6H4-4-NMe2)2H]",

abstract = "Terminal alkynes (R-C\{triple bond, long\}C-H, R = 1-naphthyl, 9-anthryl, 4-Me2N-C6H4-, or the longer analogue, 4-(4-Me2N-C6H4-C\{triple bond, long\}C-)-C6H4-) react with [Rh(PMe3)4Me] at ambient temperature, with loss of methane and one PMe3 ligand, to form the corresponding mer,trans-[(PMe3)3Rh(C\{triple bond, long\}CR)2H] compounds in excellent yield. In this preliminary study, the synthesis and spectroscopic characterization of the four new compounds are reported, along with the single-crystal structure of the R = 4-Me2N-C6H4 derivative.",

keywords = "Acetylide, Alkynyl, Crystal structure, Hydride, Luminescent",

author = "Xunjin ZHU and Ward, \{Richard M.\} and David Albesa-Jov{\'e} and Howard, \{Judith A.K.\} and Laurent Porr{\`e}s and Andrew Beeby and Low, \{Paul J.\} and WONG, \{Rick W K\} and Marder, \{Todd B.\}",

note = "T.B.M., J.A.K.H., A.B. and P.J.L thank One NorthEast for funding under the UIC Nanotechnology program. R.M.W. thanks EPSRC for a postgraduate studentship. ",

year = "2006",

month = jun,

day = "1",

doi = "10.1016/j.ica.2005.11.030",

language = "English",

volume = "359",

pages = "2859--2863",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier B.V.",

number = "9",

}

TY - JOUR

T1 - Synthesis of new mer,trans-rhodium(III) hydrido-bis(acetylide) complexes

T2 - Structure of mer,trans-[(PMe3)3Rh(C{triple bond, long}C-C6H4-4-NMe2)2H]

AU - ZHU, Xunjin

AU - Ward, Richard M.

AU - Albesa-Jové, David

AU - Howard, Judith A.K.

AU - Porrès, Laurent

AU - Beeby, Andrew

AU - Low, Paul J.

AU - WONG, Rick W K

AU - Marder, Todd B.

N1 - T.B.M., J.A.K.H., A.B. and P.J.L thank One NorthEast for funding under the UIC Nanotechnology program. R.M.W. thanks EPSRC for a postgraduate studentship.

PY - 2006/6/1

Y1 - 2006/6/1

N2 - Terminal alkynes (R-C{triple bond, long}C-H, R = 1-naphthyl, 9-anthryl, 4-Me2N-C6H4-, or the longer analogue, 4-(4-Me2N-C6H4-C{triple bond, long}C-)-C6H4-) react with [Rh(PMe3)4Me] at ambient temperature, with loss of methane and one PMe3 ligand, to form the corresponding mer,trans-[(PMe3)3Rh(C{triple bond, long}CR)2H] compounds in excellent yield. In this preliminary study, the synthesis and spectroscopic characterization of the four new compounds are reported, along with the single-crystal structure of the R = 4-Me2N-C6H4 derivative.

AB - Terminal alkynes (R-C{triple bond, long}C-H, R = 1-naphthyl, 9-anthryl, 4-Me2N-C6H4-, or the longer analogue, 4-(4-Me2N-C6H4-C{triple bond, long}C-)-C6H4-) react with [Rh(PMe3)4Me] at ambient temperature, with loss of methane and one PMe3 ligand, to form the corresponding mer,trans-[(PMe3)3Rh(C{triple bond, long}CR)2H] compounds in excellent yield. In this preliminary study, the synthesis and spectroscopic characterization of the four new compounds are reported, along with the single-crystal structure of the R = 4-Me2N-C6H4 derivative.

KW - Acetylide

KW - Alkynyl

KW - Crystal structure

KW - Hydride

KW - Luminescent

UR - https://www.scopus.com/pages/publications/33646534837

U2 - 10.1016/j.ica.2005.11.030

DO - 10.1016/j.ica.2005.11.030

M3 - Journal article

AN - SCOPUS:33646534837

SN - 0020-1693

VL - 359

SP - 2859

EP - 2863

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 9

ER -

Synthesis of new mer,trans-rhodium(III) hydrido-bis(acetylide) complexes: Structure of mer,trans-[(PMe₃)₃Rh(C{triple bond, long}C-C₆H₄-4-NMe₂)₂H]

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