@article{33ff3de552bc4fecb0fb47f1251980a5,
title = "Synthesis of (E)-Silyl-Acrylates via Ruthenium-Catalyzed Selective Dehydrogenative Si-H/C-H Silylation of Acrylates",
abstract = "An efficient and selective ruthenium-catalyzed dehydrogenative Si-H/C-H silylation of acrylates is described. A broad range of (E)-silylated acrylates could be easily synthesized with good functional group tolerance in moderate to excellent yields under mild conditions from hydrosilanes and acrylates. The RuHCl(CO)(PPh3)3/nbe catalytic system exhibits high stereo-, chemo-, and regio-selectivity. Furthermore, gram-scale syntheses were demonstrated, and a plausible mechanism involving the step of alkene insertion into a Ru-Si bond is proposed.",
author = "Jiawan Ye and Ping Li and Ruxin Jin and Haiyi Feng and Fanghua Cai and Jun Wang and Bin Li",
note = "We thank the Support of the Foundation of Department of Education of Guangdong Province (No: 2021ZDZX2045, 2024ZDJS036), Key Projects on Fundamental and Applied Fundamental Research of Jiangmen (2520002000133), the Foundation of Wuyi University (No: 2021WGALH06). Publisher Copyright: {\textcopyright} 2025 American Chemical Society",
year = "2025",
month = dec,
day = "15",
doi = "10.1021/acs.orglett.5c04599",
language = "English",
journal = "Organic Letters",
issn = "1523-7060",
publisher = "American Chemical Society",
}