Synthesis, crystal structures and antenna-like sensitization of visible and near infrared emission in heterobimetallic Zn-Eu and Zn-Nd Schiff base compounds

Xiaoping Yang; Richard A. Jones; Qiaoyin Wu; Michael M. Oye; Wing Kit Lo; Rick W K WONG; Archie L. Holmes

doi:10.1016/j.poly.2005.06.055

Synthesis, crystal structures and antenna-like sensitization of visible and near infrared emission in heterobimetallic Zn-Eu and Zn-Nd Schiff base compounds

Xiaoping Yang, Richard A. Jones^*, Qiaoyin Wu, Michael M. Oye, Wing Kit Lo, Rick W K WONG, Archie L. Holmes

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

77 Citations (Scopus)

Abstract

Visible and near infrared (NIR) luminescence are observed in heterobimetallic 3d-4f Schiff base complexes [ZnLEu(OAc)(NO₃) ₂] · EtOH · H₂O (2) and [ZnLNd(OAc)(NO ₃)₂(H₂O)] · EtOH (3), respectively (H₂L = N,N′-bis(5-bromo-3-methoxysalicylidene)phenylene-1,2- diamine, OAc = acetate).

Original language	English
Pages (from-to)	271-278
Number of pages	8
Journal	Polyhedron
Volume	25
Issue number	2
DOIs	https://doi.org/10.1016/j.poly.2005.06.055
Publication status	Published - 23 Jan 2006

Scopus Subject Areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

User-Defined Keywords

3d-4f Complex
Luminescence
Schiff base
X-ray crystallography
Zinc-lanthanide

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10.1016/j.poly.2005.06.055

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title = "Synthesis, crystal structures and antenna-like sensitization of visible and near infrared emission in heterobimetallic Zn-Eu and Zn-Nd Schiff base compounds",

abstract = "Visible and near infrared (NIR) luminescence are observed in heterobimetallic 3d-4f Schiff base complexes [ZnLEu(OAc)(NO3) 2] · EtOH · H2O (2) and [ZnLNd(OAc)(NO 3)2(H2O)] · EtOH (3), respectively (H2L = N,N′-bis(5-bromo-3-methoxysalicylidene)phenylene-1,2- diamine, OAc = acetate).",

keywords = "3d-4f Complex, Luminescence, Schiff base, X-ray crystallography, Zinc-lanthanide",

author = "Xiaoping Yang and Jones, {Richard A.} and Qiaoyin Wu and Oye, {Michael M.} and Lo, {Wing Kit} and WONG, {Rick W K} and Holmes, {Archie L.}",

note = "Funding Information: We thank the Robert A. Welch Foundation (Great F-816) for financial support. WKM thanks the Hong Kong Research Grants Council (HKBU 2038/02P) for financial support.",

year = "2006",

month = jan,

day = "23",

doi = "10.1016/j.poly.2005.06.055",

language = "English",

volume = "25",

pages = "271--278",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier Ltd.",

number = "2",

}

TY - JOUR

T1 - Synthesis, crystal structures and antenna-like sensitization of visible and near infrared emission in heterobimetallic Zn-Eu and Zn-Nd Schiff base compounds

AU - Yang, Xiaoping

AU - Jones, Richard A.

AU - Wu, Qiaoyin

AU - Oye, Michael M.

AU - Lo, Wing Kit

AU - WONG, Rick W K

AU - Holmes, Archie L.

N1 - Funding Information: We thank the Robert A. Welch Foundation (Great F-816) for financial support. WKM thanks the Hong Kong Research Grants Council (HKBU 2038/02P) for financial support.

PY - 2006/1/23

Y1 - 2006/1/23

N2 - Visible and near infrared (NIR) luminescence are observed in heterobimetallic 3d-4f Schiff base complexes [ZnLEu(OAc)(NO3) 2] · EtOH · H2O (2) and [ZnLNd(OAc)(NO 3)2(H2O)] · EtOH (3), respectively (H2L = N,N′-bis(5-bromo-3-methoxysalicylidene)phenylene-1,2- diamine, OAc = acetate).

AB - Visible and near infrared (NIR) luminescence are observed in heterobimetallic 3d-4f Schiff base complexes [ZnLEu(OAc)(NO3) 2] · EtOH · H2O (2) and [ZnLNd(OAc)(NO 3)2(H2O)] · EtOH (3), respectively (H2L = N,N′-bis(5-bromo-3-methoxysalicylidene)phenylene-1,2- diamine, OAc = acetate).

KW - 3d-4f Complex

KW - Luminescence

KW - Schiff base

KW - X-ray crystallography

KW - Zinc-lanthanide

UR - http://www.scopus.com/inward/record.url?scp=30144431587&partnerID=8YFLogxK

U2 - 10.1016/j.poly.2005.06.055

DO - 10.1016/j.poly.2005.06.055

M3 - Article

AN - SCOPUS:30144431587

SN - 0277-5387

VL - 25

SP - 271

EP - 278

JO - Polyhedron

JF - Polyhedron

IS - 2

ER -

Synthesis, crystal structures and antenna-like sensitization of visible and near infrared emission in heterobimetallic Zn-Eu and Zn-Nd Schiff base compounds

Abstract

Scopus Subject Areas

User-Defined Keywords

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