Synthesis, characterization, photophysics and electrochemistry of polynuclear copper(I) and gold(I) alkynyl phosphine complexes Dedicated to Professor Thomas Mak for his contribution to structural inorganic chemistry.

Hiu Suet Lo; Nianyong ZHU; Vonika Ka Man Au; Vivian Wing Wah Yam

doi:10.1016/j.poly.2014.06.006

Synthesis, characterization, photophysics and electrochemistry of polynuclear copper(I) and gold(I) alkynyl phosphine complexes Dedicated to Professor Thomas Mak for his contribution to structural inorganic chemistry.

Hiu Suet Lo, Nianyong ZHU, Vonika Ka Man Au, Vivian Wing Wah Yam^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

17 Citations (Scopus)

Abstract

A series of polynuclear copper(I) and gold(I) alkynyl complexes, [Cu₃(μ-dppm)₃(μ₃-η¹-CC-Np)₂]BF₄ (1), [Cu₃(μ-dppm)₃(μ₃-η¹-CCC₆H₄CN-4)₂]BF₄ (2) and [{AuP(Tol-p)₃(CC)}₂Np-1,5] (3), have been synthesized and shown to exhibit rich photoluminescence at ambient and low temperatures. The electrochemistry of the complexes has also been studied in detail by cyclic voltammetry.

Original language	English
Pages (from-to)	178-184
Number of pages	7
Journal	Polyhedron
Volume	83
DOIs	https://doi.org/10.1016/j.poly.2014.06.006
Publication status	Published - 24 Nov 2014

Scopus Subject Areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

User-Defined Keywords

Alkynyl
Copper(I)
Gold(I)
Luminescence
Polynuclear

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title = "Synthesis, characterization, photophysics and electrochemistry of polynuclear copper(I) and gold(I) alkynyl phosphine complexes Dedicated to Professor Thomas Mak for his contribution to structural inorganic chemistry.",

abstract = "A series of polynuclear copper(I) and gold(I) alkynyl complexes, [Cu3(μ-dppm)3(μ3-η1-CC-Np)2]BF4 (1), [Cu3(μ-dppm)3(μ3-η1-CCC6H4CN-4)2]BF4 (2) and [{AuP(Tol-p)3(CC)}2Np-1,5] (3), have been synthesized and shown to exhibit rich photoluminescence at ambient and low temperatures. The electrochemistry of the complexes has also been studied in detail by cyclic voltammetry.",

keywords = "Alkynyl, Copper(I), Gold(I), Luminescence, Polynuclear",

author = "Lo, {Hiu Suet} and Nianyong ZHU and Au, {Vonika Ka Man} and Yam, {Vivian Wing Wah}",

year = "2014",

month = nov,

day = "24",

doi = "10.1016/j.poly.2014.06.006",

language = "English",

volume = "83",

pages = "178--184",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier Ltd.",

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Synthesis, characterization, photophysics and electrochemistry of polynuclear copper(I) and gold(I) alkynyl phosphine complexes Dedicated to Professor Thomas Mak for his contribution to structural inorganic chemistry. / Lo, Hiu Suet; ZHU, Nianyong; Au, Vonika Ka Man et al.
In: Polyhedron, Vol. 83, 24.11.2014, p. 178-184.

Research output: Contribution to journal › Journal article › peer-review

TY - JOUR

T1 - Synthesis, characterization, photophysics and electrochemistry of polynuclear copper(I) and gold(I) alkynyl phosphine complexes Dedicated to Professor Thomas Mak for his contribution to structural inorganic chemistry.

AU - Lo, Hiu Suet

AU - ZHU, Nianyong

AU - Au, Vonika Ka Man

AU - Yam, Vivian Wing Wah

PY - 2014/11/24

Y1 - 2014/11/24

N2 - A series of polynuclear copper(I) and gold(I) alkynyl complexes, [Cu3(μ-dppm)3(μ3-η1-CC-Np)2]BF4 (1), [Cu3(μ-dppm)3(μ3-η1-CCC6H4CN-4)2]BF4 (2) and [{AuP(Tol-p)3(CC)}2Np-1,5] (3), have been synthesized and shown to exhibit rich photoluminescence at ambient and low temperatures. The electrochemistry of the complexes has also been studied in detail by cyclic voltammetry.

AB - A series of polynuclear copper(I) and gold(I) alkynyl complexes, [Cu3(μ-dppm)3(μ3-η1-CC-Np)2]BF4 (1), [Cu3(μ-dppm)3(μ3-η1-CCC6H4CN-4)2]BF4 (2) and [{AuP(Tol-p)3(CC)}2Np-1,5] (3), have been synthesized and shown to exhibit rich photoluminescence at ambient and low temperatures. The electrochemistry of the complexes has also been studied in detail by cyclic voltammetry.

KW - Alkynyl

KW - Copper(I)

KW - Gold(I)

KW - Luminescence

KW - Polynuclear

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U2 - 10.1016/j.poly.2014.06.006

DO - 10.1016/j.poly.2014.06.006

M3 - Journal article

AN - SCOPUS:84908153675

SN - 0277-5387

VL - 83

SP - 178

EP - 184

JO - Polyhedron

JF - Polyhedron

ER -

Synthesis, characterization, photophysics and electrochemistry of polynuclear copper(I) and gold(I) alkynyl phosphine complexes Dedicated to Professor Thomas Mak for his contribution to structural inorganic chemistry.

Abstract

Scopus Subject Areas

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