Synthesis, characterization, photophysical and photovoltaic properties of new donor-acceptor platinum(II) acetylide complexes

Qian Liu; Nianyong ZHU; Cheuk Lam HO; Yingying Fu; Wai Sum Lau; Zhiyuan Xie; Lixiang Wang; Wai Yeung WONG

doi:10.1016/j.jorganchem.2015.06.017

Synthesis, characterization, photophysical and photovoltaic properties of new donor-acceptor platinum(II) acetylide complexes

Qian Liu, Nianyong ZHU, Cheuk Lam HO^*, Yingying Fu, Wai Sum Lau, Zhiyuan Xie, Lixiang Wang, Wai Yeung WONG

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

14 Citations (Scopus)

Abstract

Six new solution processable platinum(II) acetylide donor-acceptor (D-A) triads end-capped by 4,7-di-2-thienyl-2,1,3-benzothiadiazole (DTBT) have been synthesized and characterized by photophysical and electrochemical methods. All these materials possess low bandgaps and strong UV/Vis absorption between 400 and 700 nm. Bulk heterojunction (BHJ) solar cells based on these molecules as donor materials were fabricated. The best power conversion efficiency (PCE) of 1.46% with the open-circuit voltage (V_oc) of 0.70 V, short-circuit current density (J_sc) of 6.17 mA cm^-2 and fill factor (FF) of 0.33 was achieved under illumination of an AM 1.5 solar cell simulator. These results suggest the potential use of solution-processable small molecular platinum(II)-acetylides for efficient generation in organic photovoltaic implementation.

Original language	English
Pages (from-to)	2-12
Number of pages	11
Journal	Journal of Organometallic Chemistry
Volume	812
DOIs	https://doi.org/10.1016/j.jorganchem.2015.06.017
Publication status	Published - 15 Jun 2016

Scopus Subject Areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

User-Defined Keywords

Acetylide
Bulk heterojunction solar cell
Crystal structure
Photovoltaics
Platinum

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1016/j.jorganchem.2015.06.017

Cite this

@article{7078f4bf0ccf497a9e47bbc3be53cd96,

title = "Synthesis, characterization, photophysical and photovoltaic properties of new donor-acceptor platinum(II) acetylide complexes",

abstract = "Six new solution processable platinum(II) acetylide donor-acceptor (D-A) triads end-capped by 4,7-di-2-thienyl-2,1,3-benzothiadiazole (DTBT) have been synthesized and characterized by photophysical and electrochemical methods. All these materials possess low bandgaps and strong UV/Vis absorption between 400 and 700 nm. Bulk heterojunction (BHJ) solar cells based on these molecules as donor materials were fabricated. The best power conversion efficiency (PCE) of 1.46% with the open-circuit voltage (Voc) of 0.70 V, short-circuit current density (Jsc) of 6.17 mA cm-2 and fill factor (FF) of 0.33 was achieved under illumination of an AM 1.5 solar cell simulator. These results suggest the potential use of solution-processable small molecular platinum(II)-acetylides for efficient generation in organic photovoltaic implementation.",

keywords = "Acetylide, Bulk heterojunction solar cell, Crystal structure, Photovoltaics, Platinum",

author = "Qian Liu and Nianyong ZHU and HO, {Cheuk Lam} and Yingying Fu and Lau, {Wai Sum} and Zhiyuan Xie and Lixiang Wang and WONG, {Wai Yeung}",

note = "Funding Information: We thank the National Natural Science Foundation of China (project number 51373145), Areas of Excellence Scheme, University Grants Committee of HKSAR (project No. AoE/P-03/08), Hong Kong Baptist University ( FRG2/13-14/083 ), Hong Kong Research Grants Council ( HKBU203312 ) and the Science, Technology and Innovation Committee of Shenzhen Municipality ( JCYJ20140419130507116 ) for financial support. The work was also supported by Partner State Key Laboratory of Environmental and Biological Analysis ( SKLP-14-15-P011 ) and Strategic Development Fund of HKBU . The project was also supported by the Open Research Fund of State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences.",

year = "2016",

month = jun,

day = "15",

doi = "10.1016/j.jorganchem.2015.06.017",

language = "English",

volume = "812",

pages = "2--12",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier",

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TY - JOUR

T1 - Synthesis, characterization, photophysical and photovoltaic properties of new donor-acceptor platinum(II) acetylide complexes

AU - Liu, Qian

AU - ZHU, Nianyong

AU - HO, Cheuk Lam

AU - Fu, Yingying

AU - Lau, Wai Sum

AU - Xie, Zhiyuan

AU - Wang, Lixiang

AU - WONG, Wai Yeung

N1 - Funding Information: We thank the National Natural Science Foundation of China (project number 51373145), Areas of Excellence Scheme, University Grants Committee of HKSAR (project No. AoE/P-03/08), Hong Kong Baptist University ( FRG2/13-14/083 ), Hong Kong Research Grants Council ( HKBU203312 ) and the Science, Technology and Innovation Committee of Shenzhen Municipality ( JCYJ20140419130507116 ) for financial support. The work was also supported by Partner State Key Laboratory of Environmental and Biological Analysis ( SKLP-14-15-P011 ) and Strategic Development Fund of HKBU . The project was also supported by the Open Research Fund of State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences.

PY - 2016/6/15

Y1 - 2016/6/15

N2 - Six new solution processable platinum(II) acetylide donor-acceptor (D-A) triads end-capped by 4,7-di-2-thienyl-2,1,3-benzothiadiazole (DTBT) have been synthesized and characterized by photophysical and electrochemical methods. All these materials possess low bandgaps and strong UV/Vis absorption between 400 and 700 nm. Bulk heterojunction (BHJ) solar cells based on these molecules as donor materials were fabricated. The best power conversion efficiency (PCE) of 1.46% with the open-circuit voltage (Voc) of 0.70 V, short-circuit current density (Jsc) of 6.17 mA cm-2 and fill factor (FF) of 0.33 was achieved under illumination of an AM 1.5 solar cell simulator. These results suggest the potential use of solution-processable small molecular platinum(II)-acetylides for efficient generation in organic photovoltaic implementation.

AB - Six new solution processable platinum(II) acetylide donor-acceptor (D-A) triads end-capped by 4,7-di-2-thienyl-2,1,3-benzothiadiazole (DTBT) have been synthesized and characterized by photophysical and electrochemical methods. All these materials possess low bandgaps and strong UV/Vis absorption between 400 and 700 nm. Bulk heterojunction (BHJ) solar cells based on these molecules as donor materials were fabricated. The best power conversion efficiency (PCE) of 1.46% with the open-circuit voltage (Voc) of 0.70 V, short-circuit current density (Jsc) of 6.17 mA cm-2 and fill factor (FF) of 0.33 was achieved under illumination of an AM 1.5 solar cell simulator. These results suggest the potential use of solution-processable small molecular platinum(II)-acetylides for efficient generation in organic photovoltaic implementation.

KW - Acetylide

KW - Bulk heterojunction solar cell

KW - Crystal structure

KW - Photovoltaics

KW - Platinum

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DO - 10.1016/j.jorganchem.2015.06.017

M3 - Journal article

AN - SCOPUS:84936966789

SN - 0022-328X

VL - 812

SP - 2

EP - 12

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

ER -

Synthesis, characterization, photophysical and photovoltaic properties of new donor-acceptor platinum(II) acetylide complexes

Abstract

Scopus Subject Areas

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UN SDGs

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