Synthesis, characterization, electrochemistry and photophysical studies of rhenium(I) tricarbonyl diimine complexes with carboxaldehyde alkynyl ligands Dedicated to Professor Claude Lapinte for his contribution to organometallic chemistry.

Siu Tung Lam; Nianyong ZHU; Vonika Ka Man Au; Vivian Wing Wah Yam

doi:10.1016/j.poly.2014.03.051

Synthesis, characterization, electrochemistry and photophysical studies of rhenium(I) tricarbonyl diimine complexes with carboxaldehyde alkynyl ligands Dedicated to Professor Claude Lapinte for his contribution to organometallic chemistry.

Siu Tung Lam
, Nianyong ZHU
, Vonika Ka Man Au
, Vivian Wing Wah Yam^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

19 Citations (Scopus)

Abstract

A class of rhenium(I) tricarbonyl diimine complexes with carboxaldehyde alkynyl ligands, [Re(CO)₃(N^N)(CC-C₆H₄-CHO)] (N^N = α,α′-diimine ligand), has been successfully synthesized and characterized, and the X-ray crystal structure of one of the complexes has been determined. Electrochemical and photophysical studies have been performed to study the effect of the variation of the diimine ligand on the redox and optical properties of the rhenium(I) complexes.

Original language	English
Pages (from-to)	10-16
Number of pages	7
Journal	Polyhedron
Volume	86
DOIs	https://doi.org/10.1016/j.poly.2014.03.051
Publication status	Published - 28 Jan 2015

User-Defined Keywords

Alkynyl
Diimine
Electrochemistry
Photoluminescence
Rhenium(I)

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10.1016/j.poly.2014.03.051

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title = "Synthesis, characterization, electrochemistry and photophysical studies of rhenium(I) tricarbonyl diimine complexes with carboxaldehyde alkynyl ligands Dedicated to Professor Claude Lapinte for his contribution to organometallic chemistry.",

abstract = "A class of rhenium(I) tricarbonyl diimine complexes with carboxaldehyde alkynyl ligands, [Re(CO)3(N\textasciicircum{}N)(CC-C6H4-CHO)] (N\textasciicircum{}N = α,α′-diimine ligand), has been successfully synthesized and characterized, and the X-ray crystal structure of one of the complexes has been determined. Electrochemical and photophysical studies have been performed to study the effect of the variation of the diimine ligand on the redox and optical properties of the rhenium(I) complexes.",

keywords = "Alkynyl, Diimine, Electrochemistry, Photoluminescence, Rhenium(I)",

author = "Lam, \{Siu Tung\} and Nianyong ZHU and Au, \{Vonika Ka Man\} and Yam, \{Vivian Wing Wah\}",

note = "Funding Information: V.W.-W.Y. acknowledges support from the University of Hong Kong and the URC Strategic Research Theme on New Materials. This work has been supported by a grant from the Theme-Based Research Scheme (TBRS) of the Research Grants Council of the Hong Kong Special Administrative Region, China (Project No. T23-713/11). S.-T. L. acknowledges the receipt of a postgraduate studentship administered by The University of Hong Kong. ",

year = "2015",

month = jan,

day = "28",

doi = "10.1016/j.poly.2014.03.051",

language = "English",

volume = "86",

pages = "10--16",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier Ltd.",

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Synthesis, characterization, electrochemistry and photophysical studies of rhenium(I) tricarbonyl diimine complexes with carboxaldehyde alkynyl ligands Dedicated to Professor Claude Lapinte for his contribution to organometallic chemistry. / Lam, Siu Tung; ZHU, Nianyong; Au, Vonika Ka Man et al.
In: Polyhedron, Vol. 86, 28.01.2015, p. 10-16.

Research output: Contribution to journal › Journal article › peer-review

TY - JOUR

T1 - Synthesis, characterization, electrochemistry and photophysical studies of rhenium(I) tricarbonyl diimine complexes with carboxaldehyde alkynyl ligands Dedicated to Professor Claude Lapinte for his contribution to organometallic chemistry.

AU - Lam, Siu Tung

AU - ZHU, Nianyong

AU - Au, Vonika Ka Man

AU - Yam, Vivian Wing Wah

N1 - Funding Information: V.W.-W.Y. acknowledges support from the University of Hong Kong and the URC Strategic Research Theme on New Materials. This work has been supported by a grant from the Theme-Based Research Scheme (TBRS) of the Research Grants Council of the Hong Kong Special Administrative Region, China (Project No. T23-713/11). S.-T. L. acknowledges the receipt of a postgraduate studentship administered by The University of Hong Kong.

PY - 2015/1/28

Y1 - 2015/1/28

N2 - A class of rhenium(I) tricarbonyl diimine complexes with carboxaldehyde alkynyl ligands, [Re(CO)3(N^N)(CC-C6H4-CHO)] (N^N = α,α′-diimine ligand), has been successfully synthesized and characterized, and the X-ray crystal structure of one of the complexes has been determined. Electrochemical and photophysical studies have been performed to study the effect of the variation of the diimine ligand on the redox and optical properties of the rhenium(I) complexes.

AB - A class of rhenium(I) tricarbonyl diimine complexes with carboxaldehyde alkynyl ligands, [Re(CO)3(N^N)(CC-C6H4-CHO)] (N^N = α,α′-diimine ligand), has been successfully synthesized and characterized, and the X-ray crystal structure of one of the complexes has been determined. Electrochemical and photophysical studies have been performed to study the effect of the variation of the diimine ligand on the redox and optical properties of the rhenium(I) complexes.

KW - Alkynyl

KW - Diimine

KW - Electrochemistry

KW - Photoluminescence

KW - Rhenium(I)

UR - https://www.scopus.com/pages/publications/84920266869

U2 - 10.1016/j.poly.2014.03.051

DO - 10.1016/j.poly.2014.03.051

M3 - Journal article

AN - SCOPUS:84920266869

SN - 0277-5387

VL - 86

SP - 10

EP - 16

JO - Polyhedron

JF - Polyhedron

ER -

Synthesis, characterization, electrochemistry and photophysical studies of rhenium(I) tricarbonyl diimine complexes with carboxaldehyde alkynyl ligands Dedicated to Professor Claude Lapinte for his contribution to organometallic chemistry.

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