Synthesis, characterization and photoluminescence properties of monoporphyrinate lanthanide complexes

Hongshan S. He*, Rick W K WONG, King Fai Li, Kok Wai CHEAH

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

22 Citations (Scopus)

Abstract

Eight monoporphyrinate lanthanide complexes of the general formula [Ln(Por)(H2O)3]Cl (Ln=Yb3+ and Er3+, Por=tetraphenylporphyrin dianion (TPP2-) and its para-substituted derivatives) were prepared and characterized by elemental analyses, MS, IR and UV-Vis spectra. Photoluminescence studies showed that porphyrinate dianion absorbed the visible light, transferred the energy to lanthanide ions and enabled the later emitting in the near-infrared region. The effects of substituent and solvent on the photoluminescence efficiency were also discussed.

Original languageEnglish
Pages (from-to)81-87
Number of pages7
JournalSynthetic Metals
Volume143
Issue number1
DOIs
Publication statusPublished - 7 May 2004

Scopus Subject Areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering
  • Metals and Alloys
  • Materials Chemistry

User-Defined Keywords

  • Lanthanides
  • Luminescence
  • Porphyrinate complexes
  • Sensitizers

Fingerprint

Dive into the research topics of 'Synthesis, characterization and photoluminescence properties of monoporphyrinate lanthanide complexes'. Together they form a unique fingerprint.

Cite this