@article{5b060a7b11cc4339ae1885e1852382c8,
title = "Synthesis, characterization and luminescent properties of three-coordinate copper(I) halide complexes containing 2-(diphenylphosphino)biphenyl",
abstract = "Highly emissive three-coordinate copper halide complexes with a bidentate phosphine ligand have attracted attention. Here, a series of three-coordinate mono- and dinuclear copper halide complexes, [CuI(dpbp)2] (1) and [CuX(dpbp)]2 (dpbp = 2-(diphenylphosphino)biphenyl, X = Br (2), Cl (3)), were synthesized, and their molecular structures and photophysical properties were investigated. In the solid state, these complexes exhibit green photoluminescence with microsecond lifetimes (λmax = 515–538 nm; τ = 11.8–19.1 μs) at 298 K. The emission of the complexes originates from the (σ + X) → π* transition. All three complexes displayed good thermal stability.",
keywords = "characterization, Copper complex, luminescent property, synthesis",
author = "Lei Qi and Qian Li and Xiao Hong and Li Liu and Zhong, \{Xin Xin\} and Qiao Chen and Li, \{Fa Bao\} and Qian Liu and Qin, \{Hai Mei\} and Wong, \{Wai Yeung\}",
note = "This work was supported by the National Natural Science Foundation of China [grant number 21671061,21071049]; Natural Science Foundation of Hubei Province of China [grant number 2013CFA087]; Hubei Province High-End Talent Training Program and the Natural Science Fund for Creative Research Groups of Hubei Province of China [grant number 2014CFA015]. W.-Y.W. acknowledges the financial support from the Areas of Excellence Scheme, University Grants Committee of HKSAR, China (AoE/P-03/08) and the Hong Kong Polytechnic University. Publisher Copyright: {\textcopyright} 2016 Informa UK Limited, trading as Taylor \& Francis Group.",
year = "2016",
month = dec,
day = "16",
doi = "10.1080/00958972.2016.1239255",
language = "English",
volume = "69",
pages = "3692--3702",
journal = "Journal of Coordination Chemistry",
issn = "0095-8972",
publisher = "Taylor and Francis Ltd.",
number = "24",
}