Synthesis, Characterization and Luminescent Properties of Copper(I) Halide Complexes Containing 1-(Diphenylphosphino)naphthalene

Qian Li, Li Liu*, Xin Xin Zhong, Fa Bao Li, Abdullah M. Asiri, Khalid A. Alamry, Nianyong ZHU, Wai Yeung WONG, Hai Mei Qin

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

4 Citations (Scopus)

Abstract

Abstract: A series of neutral luminescent tetranuclear and mononuclear copper(I) halide complexes, [Cu4I4(dpna)4] (1) and [CuX(dpna)2] dpna = 1-(diphenylphosphino)naphthalene, X = Br (2), Cl (3), were synthesized, and their molecular structures and photophysical properties were investigated. Complex 1 has a cubane-like structure with four Cu atoms pseudo-tetrahedral and four I atoms serving as μ3-bridges. The coordination geometry of the copper centers in 2–3 are trigonal-planar. In the solid state, complexes 1–3 display blue photoluminescence (λmax = 423–463 nm) at 298 K. The emission of the complexes originate from the (σ+X) transition. All three complexes displayed good thermal stability. Graphical Abstract: [Figure not available: see fulltext.]

Original languageEnglish
Pages (from-to)101-109
Number of pages9
JournalJournal of Inorganic and Organometallic Polymers and Materials
Volume27
DOIs
Publication statusPublished - 1 Nov 2017

Scopus Subject Areas

  • Polymers and Plastics
  • Materials Chemistry

User-Defined Keywords

  • Halide
  • Luminescence
  • Neutral Cu(I) complexes
  • Synthesis

Fingerprint

Dive into the research topics of 'Synthesis, Characterization and Luminescent Properties of Copper(I) Halide Complexes Containing 1-(Diphenylphosphino)naphthalene'. Together they form a unique fingerprint.

Cite this