Synthesis and x-ray crystal structure of the Sm-ylide complex, [(C5H5)3SmCH2P(Me)Ph2]

Rick W K WONG; Jingwen Guan; Jinsong Ren; Qi Shen; Wing Tak Wong

doi:10.1016/S0277-5387(00)80129-1

Synthesis and x-ray crystal structure of the Sm-ylide complex, [(C₅H₅)₃SmCH₂P(Me)Ph₂]

Rick W K WONG^*, Jingwen Guan, Jinsong Ren, Qi Shen, Wing Tak Wong

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

The interaction of (C₅H₅)₂SmCl·LiCl with one equivalent of Li[(CH₂)(CH₂) PPh₂] in refluxing tetrahydrofuran gives the yellow complex [(C₅H₅)₃SmCH₂P (Me)Ph₂] in 30% yield. The compound has been fully characterized by analytical, spectroscopic and X-ray diffraction methods.

Original language	English
Pages (from-to)	2749-2751
Number of pages	3
Journal	Polyhedron
Volume	12
Issue number	22
DOIs	https://doi.org/10.1016/S0277-5387(00)80129-1
Publication status	Published - Nov 1993

Scopus Subject Areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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@article{b220a8da3fa44c1094f8f44b53dc35f5,

title = "Synthesis and x-ray crystal structure of the Sm-ylide complex, [(C5H5)3SmCH2P(Me)Ph2]",

abstract = "The interaction of (C5H5)2SmCl·LiCl with one equivalent of Li[(CH2)(CH2) PPh2] in refluxing tetrahydrofuran gives the yellow complex [(C5H5)3SmCH2P (Me)Ph2] in 30% yield. The compound has been fully characterized by analytical, spectroscopic and X-ray diffraction methods.",

author = "WONG, {Rick W K} and Jingwen Guan and Jinsong Ren and Qi Shen and Wong, {Wing Tak}",

note = "Funding Information: Acknowledgement-W.-K. Wong thankst he Hong Kong Baptist College, the Hong Kong Research Grant Council, and the Croucher Foundation for financial support. W.-T. Wong thanks the Hong Kong Research Grant Council and the University of Hong Kong for financial support.",

year = "1993",

month = nov,

doi = "10.1016/S0277-5387(00)80129-1",

language = "English",

volume = "12",

pages = "2749--2751",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier Ltd.",

number = "22",

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TY - JOUR

T1 - Synthesis and x-ray crystal structure of the Sm-ylide complex, [(C5H5)3SmCH2P(Me)Ph2]

AU - WONG, Rick W K

AU - Guan, Jingwen

AU - Ren, Jinsong

AU - Shen, Qi

AU - Wong, Wing Tak

N1 - Funding Information: Acknowledgement-W.-K. Wong thankst he Hong Kong Baptist College, the Hong Kong Research Grant Council, and the Croucher Foundation for financial support. W.-T. Wong thanks the Hong Kong Research Grant Council and the University of Hong Kong for financial support.

PY - 1993/11

Y1 - 1993/11

N2 - The interaction of (C5H5)2SmCl·LiCl with one equivalent of Li[(CH2)(CH2) PPh2] in refluxing tetrahydrofuran gives the yellow complex [(C5H5)3SmCH2P (Me)Ph2] in 30% yield. The compound has been fully characterized by analytical, spectroscopic and X-ray diffraction methods.

AB - The interaction of (C5H5)2SmCl·LiCl with one equivalent of Li[(CH2)(CH2) PPh2] in refluxing tetrahydrofuran gives the yellow complex [(C5H5)3SmCH2P (Me)Ph2] in 30% yield. The compound has been fully characterized by analytical, spectroscopic and X-ray diffraction methods.

UR - http://www.scopus.com/inward/record.url?scp=0011634431&partnerID=8YFLogxK

U2 - 10.1016/S0277-5387(00)80129-1

DO - 10.1016/S0277-5387(00)80129-1

M3 - Article

AN - SCOPUS:0011634431

SN - 0277-5387

VL - 12

SP - 2749

EP - 2751

JO - Polyhedron

JF - Polyhedron

IS - 22

ER -

Synthesis and x-ray crystal structure of the Sm-ylide complex, [(C₅H₅)₃SmCH₂P(Me)Ph₂]

Abstract

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