Synthesis and x-ray crystal structure of [Li(C4H8O)4] [Yb(NPh2)4]

Rick W K WONG*, Lilu Zhang, Feng Xue, Thomas C.W. Mak

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

21 Citations (Scopus)

Abstract

The interaction of Yb(NPh2)2Cl with one equivalent of Li[(CH2) (CH2)PPh2] in tetrahydrofuran gave the unexpected dark red complex [Li(C4H8O)4][Yb(NPh2)4] (1) in 30% yield. An X-ray diffraction study reveals that the lanthanide-amide ate complex is composed of a discrete cation [Li(C4H8O)4]+ and a discrete homoleptic tetrahedral Yb-amide anion [Yb(NPh2)4]-.

Original languageEnglish
Pages (from-to)345-347
Number of pages3
JournalPolyhedron
Volume16
Issue number2
DOIs
Publication statusPublished - 1997

Scopus Subject Areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

User-Defined Keywords

  • Diphenylamide
  • Discrete homoleptic amide anion
  • Homoleptic amide complex
  • Lanthanide-amide ate complex
  • Structure
  • Ytterbium(III)

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