Synthesis and X-ray crystal structure of (cis-PdCl2)2[Ph2PNH)(NH)CC6H4C(NH)(NHPPh2)]·6DMF

Rick W K WONG; Tao Jiang; Daniel W J KWONG; Wing Tak Wong

doi:10.1016/0277-5387(95)00033-O

Synthesis and X-ray crystal structure of (cis-PdCl₂)₂[Ph₂PNH)(NH)CC₆H₄C(NH)(NHPPh₂)]·6DMF

Rick W K WONG^*, Tao Jiang, Daniel W J KWONG, Wing Tak Wong

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

The interaction of 1,4-phenylenebis[N-(diphenylphosphino-N′,N′-bis(trimethylsily)amidine], (Ph₂PN)[N(SiMe₃)₂]CC₆H₄C[N(SiMe₃)₂](PPh₂), with 2 equaivalents of PdCl₂(PhCN)₂ in THF gives (cis-PdCl₂)₂[(Ph₂PNH)(NH)CC₆H₄C(NH)(NHPPh₂)] in moderate yield. The compound has C₂ symmetry and has been fully characterized by analytical, spectroscopic and X-ray diffraction methods.

Original language	English
Pages (from-to)	1109-1111
Number of pages	3
Journal	Polyhedron
Volume	14
Issue number	8
DOIs	https://doi.org/10.1016/0277-5387(95)00033-O
Publication status	Published - Apr 1995

Scopus Subject Areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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@article{0666d10dee874323a3d36a449912c223,

title = "Synthesis and X-ray crystal structure of (cis-PdCl2)2[Ph2PNH)(NH)CC6H4C(NH)(NHPPh2)]·6DMF",

abstract = "The interaction of 1,4-phenylenebis[N-(diphenylphosphino-N′,N′-bis(trimethylsily)amidine], (Ph2PN)[N(SiMe3)2]CC6H4C[N(SiMe3)2](PPh2), with 2 equaivalents of PdCl2(PhCN)2 in THF gives (cis-PdCl2)2[(Ph2PNH)(NH)CC6H4C(NH)(NHPPh2)] in moderate yield. The compound has C2 symmetry and has been fully characterized by analytical, spectroscopic and X-ray diffraction methods.",

author = "WONG, {Rick W K} and Tao Jiang and KWONG, {Daniel W J} and Wong, {Wing Tak}",

note = "Funding Information: Kwong thank the Hong Kong Baptist College and the Hong Kong Research Grant Council for financial support. Wing-Tak Wong thanks the Hong Kong Research Grant Council and the University of Hong Kong for financial support.",

year = "1995",

month = apr,

doi = "10.1016/0277-5387(95)00033-O",

language = "English",

volume = "14",

pages = "1109--1111",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier Ltd.",

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T1 - Synthesis and X-ray crystal structure of (cis-PdCl2)2[Ph2PNH)(NH)CC6H4C(NH)(NHPPh2)]·6DMF

AU - WONG, Rick W K

AU - Jiang, Tao

AU - KWONG, Daniel W J

AU - Wong, Wing Tak

N1 - Funding Information: Kwong thank the Hong Kong Baptist College and the Hong Kong Research Grant Council for financial support. Wing-Tak Wong thanks the Hong Kong Research Grant Council and the University of Hong Kong for financial support.

PY - 1995/4

Y1 - 1995/4

N2 - The interaction of 1,4-phenylenebis[N-(diphenylphosphino-N′,N′-bis(trimethylsily)amidine], (Ph2PN)[N(SiMe3)2]CC6H4C[N(SiMe3)2](PPh2), with 2 equaivalents of PdCl2(PhCN)2 in THF gives (cis-PdCl2)2[(Ph2PNH)(NH)CC6H4C(NH)(NHPPh2)] in moderate yield. The compound has C2 symmetry and has been fully characterized by analytical, spectroscopic and X-ray diffraction methods.

AB - The interaction of 1,4-phenylenebis[N-(diphenylphosphino-N′,N′-bis(trimethylsily)amidine], (Ph2PN)[N(SiMe3)2]CC6H4C[N(SiMe3)2](PPh2), with 2 equaivalents of PdCl2(PhCN)2 in THF gives (cis-PdCl2)2[(Ph2PNH)(NH)CC6H4C(NH)(NHPPh2)] in moderate yield. The compound has C2 symmetry and has been fully characterized by analytical, spectroscopic and X-ray diffraction methods.

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U2 - 10.1016/0277-5387(95)00033-O

DO - 10.1016/0277-5387(95)00033-O

M3 - Article

AN - SCOPUS:0346652682

VL - 14

SP - 1109

EP - 1111

JO - Polyhedron

JF - Polyhedron

SN - 0277-5387

IS - 8

ER -

Synthesis and X-ray crystal structure of (cis-PdCl₂)₂[Ph₂PNH)(NH)CC₆H₄C(NH)(NHPPh₂)]·6DMF

Abstract

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