Synthesis and X-ray crystal structure of (cis-PdCl2)2[Ph2PNH)(NH)CC6H4C(NH)(NHPPh2)]·6DMF

Rick W K WONG*, Tao Jiang, Daniel W J KWONG, Wing Tak Wong

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

7 Citations (Scopus)

Abstract

The interaction of 1,4-phenylenebis[N-(diphenylphosphino-N′,N′-bis(trimethylsily)amidine], (Ph2PN)[N(SiMe3)2]CC6H4C[N(SiMe3)2](PPh2), with 2 equaivalents of PdCl2(PhCN)2 in THF gives (cis-PdCl2)2[(Ph2PNH)(NH)CC6H4C(NH)(NHPPh2)] in moderate yield. The compound has C2 symmetry and has been fully characterized by analytical, spectroscopic and X-ray diffraction methods.

Original languageEnglish
Pages (from-to)1109-1111
Number of pages3
JournalPolyhedron
Volume14
Issue number8
DOIs
Publication statusPublished - Apr 1995

Scopus Subject Areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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