Synthesis and X-ray crystal structure of a hexanuclear silver(I) complex with non-chelating tri- and tetra-dentate bridging o-(diphenylphosphino)benzoate ligands

Rick W K WONG; Lilu Zhang; Wing Tak Wong

doi:10.1039/a708227d

Synthesis and X-ray crystal structure of a hexanuclear silver(I) complex with non-chelating tri- and tetra-dentate bridging o-(diphenylphosphino)benzoate ligands

Rick W K WONG^*, Lilu Zhang, Wing Tak Wong

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

12 Citations (Scopus)

Abstract

Single crystal X-ray analysis of the hexanuclear silver(I) complex Ag₆[o-Ph₂P(C₆H₄CO ₂)-O,P]₆, synthesized by treatment of Ag(CF₃SO₃) with N(CH₂CH₂NH₂)₃, 1,3-dicyclohexylcarbodiimide (DCC) and o-Ph₂PC₆H₄(CO₂H) in 1:1:3:3 molar ratio in ethanol, shows that the complex is centrosymmetric and consists of three independent silver(I) centres linking together via non-chelating tri- and tetradentate bridging o-(diphenylphosphino)benzoate groups.

Original language	English
Pages (from-to)	673-674
Number of pages	2
Journal	Chemical Communications
Issue number	6
DOIs	https://doi.org/10.1039/a708227d
Publication status	Published - 21 Mar 1998

Scopus Subject Areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "Synthesis and X-ray crystal structure of a hexanuclear silver(I) complex with non-chelating tri- and tetra-dentate bridging o-(diphenylphosphino)benzoate ligands",

abstract = "Single crystal X-ray analysis of the hexanuclear silver(I) complex Ag6[o-Ph2P(C6H4CO 2)-O,P]6, synthesized by treatment of Ag(CF3SO3) with N(CH2CH2NH2)3, 1,3-dicyclohexylcarbodiimide (DCC) and o-Ph2PC6H4(CO2H) in 1:1:3:3 molar ratio in ethanol, shows that the complex is centrosymmetric and consists of three independent silver(I) centres linking together via non-chelating tri- and tetradentate bridging o-(diphenylphosphino)benzoate groups.",

author = "WONG, {Rick W K} and Lilu Zhang and Wong, {Wing Tak}",

year = "1998",

month = mar,

day = "21",

doi = "10.1039/a708227d",

language = "English",

pages = "673--674",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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T1 - Synthesis and X-ray crystal structure of a hexanuclear silver(I) complex with non-chelating tri- and tetra-dentate bridging o-(diphenylphosphino)benzoate ligands

AU - WONG, Rick W K

AU - Zhang, Lilu

AU - Wong, Wing Tak

PY - 1998/3/21

Y1 - 1998/3/21

N2 - Single crystal X-ray analysis of the hexanuclear silver(I) complex Ag6[o-Ph2P(C6H4CO 2)-O,P]6, synthesized by treatment of Ag(CF3SO3) with N(CH2CH2NH2)3, 1,3-dicyclohexylcarbodiimide (DCC) and o-Ph2PC6H4(CO2H) in 1:1:3:3 molar ratio in ethanol, shows that the complex is centrosymmetric and consists of three independent silver(I) centres linking together via non-chelating tri- and tetradentate bridging o-(diphenylphosphino)benzoate groups.

AB - Single crystal X-ray analysis of the hexanuclear silver(I) complex Ag6[o-Ph2P(C6H4CO 2)-O,P]6, synthesized by treatment of Ag(CF3SO3) with N(CH2CH2NH2)3, 1,3-dicyclohexylcarbodiimide (DCC) and o-Ph2PC6H4(CO2H) in 1:1:3:3 molar ratio in ethanol, shows that the complex is centrosymmetric and consists of three independent silver(I) centres linking together via non-chelating tri- and tetradentate bridging o-(diphenylphosphino)benzoate groups.

UR - http://www.scopus.com/inward/record.url?scp=0002909391&partnerID=8YFLogxK

U2 - 10.1039/a708227d

DO - 10.1039/a708227d

M3 - Journal article

AN - SCOPUS:0002909391

SN - 1359-7345

SP - 673

EP - 674

JO - Chemical Communications

JF - Chemical Communications

IS - 6

ER -

Synthesis and X-ray crystal structure of a hexanuclear silver(I) complex with non-chelating tri- and tetra-dentate bridging o-(diphenylphosphino)benzoate ligands

Abstract

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