Synthesis and structure of chiral metal complexes of polyazacycloalkane ligands incorporating phosphinic acid donors

Eleanor Cole; David Parker; George Ferguson; John F. Gallagher; Branko Kaitner

doi:10.1039/C39910001473

Synthesis and structure of chiral metal complexes of polyazacycloalkane ligands incorporating phosphinic acid donors

Eleanor Cole, David Parker, George Ferguson, John F. Gallagher, Branko Kaitner

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

40 Citations (Scopus)

Abstract

The chiral copper(II) and gallium(III) complexes of a triazatris(phenylphosphinic acid) ligand have very similar structures: the anionic copper complex possesses C₃ symmetry, shows no Jahn-Teller distortion at 293 K nor at 123 K and is resistant to protonation.

Original language	English
Pages (from-to)	1473-1475
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	20
DOIs	https://doi.org/10.1039/C39910001473
Publication status	Published - Oct 1991

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@article{9223823ab39e474e83a988e9f80c902e,

title = "Synthesis and structure of chiral metal complexes of polyazacycloalkane ligands incorporating phosphinic acid donors",

abstract = "The chiral copper(II) and gallium(III) complexes of a triazatris(phenylphosphinic acid) ligand have very similar structures: the anionic copper complex possesses C3 symmetry, shows no Jahn-Teller distortion at 293 K nor at 123 K and is resistant to protonation.",

author = "Eleanor Cole and David Parker and George Ferguson and Gallagher, {John F.} and Branko Kaitner",

year = "1991",

month = oct,

doi = "10.1039/C39910001473",

language = "English",

pages = "1473--1475",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Royal Society of Chemistry",

number = "20",

}

TY - JOUR

T1 - Synthesis and structure of chiral metal complexes of polyazacycloalkane ligands incorporating phosphinic acid donors

AU - Cole, Eleanor

AU - Parker, David

AU - Ferguson, George

AU - Gallagher, John F.

AU - Kaitner, Branko

PY - 1991/10

Y1 - 1991/10

N2 - The chiral copper(II) and gallium(III) complexes of a triazatris(phenylphosphinic acid) ligand have very similar structures: the anionic copper complex possesses C3 symmetry, shows no Jahn-Teller distortion at 293 K nor at 123 K and is resistant to protonation.

AB - The chiral copper(II) and gallium(III) complexes of a triazatris(phenylphosphinic acid) ligand have very similar structures: the anionic copper complex possesses C3 symmetry, shows no Jahn-Teller distortion at 293 K nor at 123 K and is resistant to protonation.

UR - http://www.scopus.com/inward/record.url?scp=0026009538&partnerID=8YFLogxK

U2 - 10.1039/C39910001473

DO - 10.1039/C39910001473

M3 - Journal article

AN - SCOPUS:0026009538

SN - 0022-4936

SP - 1473

EP - 1475

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 20

ER -

Synthesis and structure of chiral metal complexes of polyazacycloalkane ligands incorporating phosphinic acid donors

Abstract

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