@article{4282724997384af49c7ba3de120d9447,
title = "Synthesis and photoelectric properties of new Dawson-type polyoxometalate-based dimeric and oligomeric Pt(ii)-acetylide inorganic-organic hybrids",
abstract = "A new synthesis route for preparing Dawson-type polyoxometalate (POM) based inorganic-organic hybrid materials is presented. Two new heteropolytungstate-based dimeric and oligomeric Pt(ii) acetylide inorganic-organic hybrid compounds (2PtOD and PPtOD) were prepared by Hagihara's dehydrohalogenating coupling of a terminal diacetylene POM hybrid containing diphosphoryl functionality and an appropriate platinum(ii) halide precursor. This method provides a rigid covalent linkage between the POM and the organometallic Pt(ii) acetylide moiety. The redox potential of the polyanion can be tuned by grafting the organic and organometallic groups on it. The photoelectric properties of hybrid LB films derived from these inorganic-organic composites were studied.",
author = "Li Liu and Lei Hu and Qian Liu and Du, {Zu Liang} and Li, {Fa Bao} and Li, {Guang Hua} and Zhu, {Xun Jin} and Wong, {Wai Yeung} and Lei Wang and Hua Li",
note = "Funding information: This work was supported by the National Natural Science Foundation of China (no. 21071049 and 51373145), Natural Science Foundation of Hubei Province of China (2013CFA087, 2014CFB550), Hubei Province High-End Talent Training Program and the Natural Science Fund for Creative Research Groups of Hubei Province of China (2014CFA015). W.-Y. Wong acknowledges the financial support from the National Basic Research Program of China (973 Program) (2013CB834702), Hong Kong Research Grants Council (HKBU203313 and HKUST2/CRF/10), Areas of Excellence Scheme, University Grants Committee of HKSAR, China (project no. AoE/P-03/08) and Hong Kong Baptist University (FRG2/12-13/083). H. Li thanks the 111 Project and the Beijing Engineering Research Center of Food Environment and Public Health from Minzu University of China (no. B08044 and no. 10301-01404026) for financial support. The work was also supported by the Partner State Key Laboratory of Environmental and Biological Analysis and the Strategic Development Fund of HKBU. Publisher copyright: {\textcopyright} The Royal Society of Chemistry 2015",
year = "2015",
month = jan,
day = "7",
doi = "10.1039/c4dt02504k",
language = "English",
volume = "44",
pages = "306--315",
journal = "Dalton Transactions",
issn = "1477-9226",
publisher = "Royal Society of Chemistry",
number = "1",
}