Synthesis and lithium transport in ionically conducting crown ether polymers

L. Collie; D. Parker; C. Tachon; H. V.St A. Hubbard; G. R. Davies; I. M. Ward; S. C. Wellings

doi:10.1016/0032-3861(93)90877-D

Synthesis and lithium transport in ionically conducting crown ether polymers

L. Collie
, D. Parker^*
, C. Tachon
, H. V.St A. Hubbard
, G. R. Davies
, I. M. Ward
, S. C. Wellings

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

20 Citations (Scopus)

Abstract

The synthesis and characterization of a series of crown ether 'comb-branch' polymers is reported wherein [12]- and [14]-ring lithium binding units have been linked to a polyacrylate or polymethacrylate backbone via a simple ester link or a C₆ or oxydiethylene chain. Preliminary data on glass transition temperature, T_g, and conductivity reveal a relative insensitivity of T_g to added lithium in the [14] series and higher conductivities in the [12]-O₄ series.

Original language	English
Pages (from-to)	1541-1543
Number of pages	3
Journal	Polymer
Volume	34
Issue number	7
DOIs	https://doi.org/10.1016/0032-3861(93)90877-D
Publication status	Published - Apr 1993

User-Defined Keywords

crown ether
doping
ionic conduction
lithium
polymethacrylate

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10.1016/0032-3861(93)90877-D

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@article{c0a206a0cc38487fa955d7c13b87a4c5,

title = "Synthesis and lithium transport in ionically conducting crown ether polymers",

abstract = "The synthesis and characterization of a series of crown ether 'comb-branch' polymers is reported wherein [12]- and [14]-ring lithium binding units have been linked to a polyacrylate or polymethacrylate backbone via a simple ester link or a C6 or oxydiethylene chain. Preliminary data on glass transition temperature, Tg, and conductivity reveal a relative insensitivity of Tg to added lithium in the [14] series and higher conductivities in the [12]-O4 series.",

keywords = "crown ether, doping, ionic conduction, lithium, polymethacrylate",

author = "L. Collie and D. Parker and C. Tachon and Hubbard, \{H. V.St A.\} and Davies, \{G. R.\} and Ward, \{I. M.\} and Wellings, \{S. C.\}",

note = "Publisher Copyright: {\textcopyright} 1993 Published by Elsevier Ltd. ",

year = "1993",

month = apr,

doi = "10.1016/0032-3861(93)90877-D",

language = "English",

volume = "34",

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journal = "Polymer",

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TY - JOUR

T1 - Synthesis and lithium transport in ionically conducting crown ether polymers

AU - Collie, L.

AU - Parker, D.

AU - Tachon, C.

AU - Hubbard, H. V.St A.

AU - Davies, G. R.

AU - Ward, I. M.

AU - Wellings, S. C.

PY - 1993/4

Y1 - 1993/4

N2 - The synthesis and characterization of a series of crown ether 'comb-branch' polymers is reported wherein [12]- and [14]-ring lithium binding units have been linked to a polyacrylate or polymethacrylate backbone via a simple ester link or a C6 or oxydiethylene chain. Preliminary data on glass transition temperature, Tg, and conductivity reveal a relative insensitivity of Tg to added lithium in the [14] series and higher conductivities in the [12]-O4 series.

AB - The synthesis and characterization of a series of crown ether 'comb-branch' polymers is reported wherein [12]- and [14]-ring lithium binding units have been linked to a polyacrylate or polymethacrylate backbone via a simple ester link or a C6 or oxydiethylene chain. Preliminary data on glass transition temperature, Tg, and conductivity reveal a relative insensitivity of Tg to added lithium in the [14] series and higher conductivities in the [12]-O4 series.

KW - crown ether

KW - doping

KW - ionic conduction

KW - lithium

KW - polymethacrylate

UR - https://www.scopus.com/pages/publications/0000470977

U2 - 10.1016/0032-3861(93)90877-D

DO - 10.1016/0032-3861(93)90877-D

M3 - Journal article

AN - SCOPUS:0000470977

SN - 0032-3861

VL - 34

SP - 1541

EP - 1543

JO - Polymer

JF - Polymer

IS - 7

ER -

Synthesis and lithium transport in ionically conducting crown ether polymers

Abstract

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