Synthesis and crystal structure of the complex cis-1,3-bis(diphenylphosphino)dicyclopentadiene tetracarbonylmolybdenum

Rick W K WONG; Fong Lung Chow; Hua Chen; Thomas C.W. Mak

doi:10.1016/0022-328X(89)80104-4

Synthesis and crystal structure of the complex cis-1,3-bis(diphenylphosphino)dicyclopentadiene tetracarbonylmolybdenum

Rick W K WONG^*, Fong Lung Chow, Hua Chen, Thomas C.W. Mak

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

2 Citations (Scopus)

Abstract

The interaction of cis-Mo(CO)₄(Ph₂PCl)₂ with 2 equivalents of (C₅H₅)Tl in refluxing toluene gives the complex cis-1,3-bis(diphenylphosphino)(dicyclopendadiene(tetracarbonyl)molybdenum in high yield. The compound has been fully characterized by analytical, spectroscopic, and X-ray diffraction methods. A mechanism for the formation of the complex is proposed.

Original language	English
Pages (from-to)	C65-C68
Number of pages	4
Journal	Journal of Organometallic Chemistry
Volume	377
Issue number	2-3
DOIs	https://doi.org/10.1016/0022-328X(89)80104-4
Publication status	Published - 12 Nov 1989

Scopus Subject Areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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@article{9c2928fd27ca4d4294d9cde9fddd81e8,

title = "Synthesis and crystal structure of the complex cis-1,3-bis(diphenylphosphino)dicyclopentadiene tetracarbonylmolybdenum",

abstract = "The interaction of cis-Mo(CO)4(Ph2PCl)2 with 2 equivalents of (C5H5)Tl in refluxing toluene gives the complex cis-1,3-bis(diphenylphosphino)(dicyclopendadiene(tetracarbonyl)molybdenum in high yield. The compound has been fully characterized by analytical, spectroscopic, and X-ray diffraction methods. A mechanism for the formation of the complex is proposed.",

author = "WONG, {Rick W K} and {Lung Chow}, Fong and Hua Chen and Mak, {Thomas C.W.}",

year = "1989",

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doi = "10.1016/0022-328X(89)80104-4",

language = "English",

volume = "377",

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journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

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number = "2-3",

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TY - JOUR

T1 - Synthesis and crystal structure of the complex cis-1,3-bis(diphenylphosphino)dicyclopentadiene tetracarbonylmolybdenum

AU - WONG, Rick W K

AU - Lung Chow, Fong

AU - Chen, Hua

AU - Mak, Thomas C.W.

PY - 1989/11/12

Y1 - 1989/11/12

N2 - The interaction of cis-Mo(CO)4(Ph2PCl)2 with 2 equivalents of (C5H5)Tl in refluxing toluene gives the complex cis-1,3-bis(diphenylphosphino)(dicyclopendadiene(tetracarbonyl)molybdenum in high yield. The compound has been fully characterized by analytical, spectroscopic, and X-ray diffraction methods. A mechanism for the formation of the complex is proposed.

AB - The interaction of cis-Mo(CO)4(Ph2PCl)2 with 2 equivalents of (C5H5)Tl in refluxing toluene gives the complex cis-1,3-bis(diphenylphosphino)(dicyclopendadiene(tetracarbonyl)molybdenum in high yield. The compound has been fully characterized by analytical, spectroscopic, and X-ray diffraction methods. A mechanism for the formation of the complex is proposed.

UR - http://www.scopus.com/inward/record.url?scp=33745052665&partnerID=8YFLogxK

U2 - 10.1016/0022-328X(89)80104-4

DO - 10.1016/0022-328X(89)80104-4

M3 - Journal article

AN - SCOPUS:33745052665

SN - 0022-328X

VL - 377

SP - C65-C68

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 2-3

ER -

Synthesis and crystal structure of the complex cis-1,3-bis(diphenylphosphino)dicyclopentadiene tetracarbonylmolybdenum

Abstract

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