Synthesis and complexation behaviour of an effective octadentate complexone 1,4,7,10-tetraazacyclododecane-1,4,7,10-tetrakis[methylene(methylphosphinic acid)]

Christopher J. Broan; Karl J. Jankowski; Ritu Kataky; David Parker; Amanda M. Randall; Alice Harrison

doi:10.1039/C39900001739

Synthesis and complexation behaviour of an effective octadentate complexone 1,4,7,10-tetraazacyclododecane-1,4,7,10-tetrakis[methylene(methylphosphinic acid)]

Christopher J. Broan
, Karl J. Jankowski
, Ritu Kataky
, David Parker
, Amanda M. Randall
, Alice Harrison

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

35 Citations (Scopus)

Abstract

The title ligand and a C-functionalised analogue have been prepared; the ligand is very strongly basic [pK_a LH⁺, LH²⁺ < 14 (298 K)] and forms remarkably stable complexes with yttrium and calcium.

Original language	English
Pages (from-to)	1739-1741
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	23
DOIs	https://doi.org/10.1039/C39900001739
Publication status	Published - Dec 1990

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@article{aafe3870b06c40a9a197eba340095f56,

title = "Synthesis and complexation behaviour of an effective octadentate complexone 1,4,7,10-tetraazacyclododecane-1,4,7,10-tetrakis[methylene(methylphosphinic acid)]",

abstract = "The title ligand and a C-functionalised analogue have been prepared; the ligand is very strongly basic [pKa LH+, LH2+ < 14 (298 K)] and forms remarkably stable complexes with yttrium and calcium.",

author = "Broan, \{Christopher J.\} and Jankowski, \{Karl J.\} and Ritu Kataky and David Parker and Randall, \{Amanda M.\} and Alice Harrison",

year = "1990",

month = dec,

doi = "10.1039/C39900001739",

language = "English",

pages = "1739--1741",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Royal Society of Chemistry",

number = "23",

}

Synthesis and complexation behaviour of an effective octadentate complexone 1,4,7,10-tetraazacyclododecane-1,4,7,10-tetrakis[methylene(methylphosphinic acid)]. / Broan, Christopher J.; Jankowski, Karl J.; Kataky, Ritu et al.
In: Journal of the Chemical Society, Chemical Communications, No. 23, 12.1990, p. 1739-1741.

Research output: Contribution to journal › Journal article › peer-review

TY - JOUR

T1 - Synthesis and complexation behaviour of an effective octadentate complexone 1,4,7,10-tetraazacyclododecane-1,4,7,10-tetrakis[methylene(methylphosphinic acid)]

AU - Broan, Christopher J.

AU - Jankowski, Karl J.

AU - Kataky, Ritu

AU - Parker, David

AU - Randall, Amanda M.

AU - Harrison, Alice

PY - 1990/12

Y1 - 1990/12

N2 - The title ligand and a C-functionalised analogue have been prepared; the ligand is very strongly basic [pKa LH+, LH2+ < 14 (298 K)] and forms remarkably stable complexes with yttrium and calcium.

AB - The title ligand and a C-functionalised analogue have been prepared; the ligand is very strongly basic [pKa LH+, LH2+ < 14 (298 K)] and forms remarkably stable complexes with yttrium and calcium.

UR - https://www.scopus.com/pages/publications/37049090077

U2 - 10.1039/C39900001739

DO - 10.1039/C39900001739

M3 - Journal article

AN - SCOPUS:37049090077

SN - 0022-4936

SP - 1739

EP - 1741

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 23

ER -

Synthesis and complexation behaviour of an effective octadentate complexone 1,4,7,10-tetraazacyclododecane-1,4,7,10-tetrakis[methylene(methylphosphinic acid)]

Abstract

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