Synthesis and characterization of silver(I) complexes [AgL] 2[BF4]2 and [Ag(OAc)L]∞ [L = (CH2NHCOC2H4PPh2)2]

Yat Li; Ka Fu Yung; Hoi Shan Chan; Wing Tak Wong; Rick W K WONG; Man Chung Tse

doi:10.1016/j.inoche.2003.08.007

Synthesis and characterization of silver(I) complexes [AgL] ₂[BF₄]₂ and [Ag(OAc)L]_∞ [L = (CH₂NHCOC₂H₄PPh₂)₂]

Yat Li, Ka Fu Yung, Hoi Shan Chan, Wing Tak Wong^*, Rick W K WONG, Man Chung Tse

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

6 Citations (Scopus)

Abstract

The interaction of (CH₂NHCOC₂H₄PPh ₂)₂, L, with one equivalent of AgBF₄ and AgOAc gave [AgL]₂[BF₄]₂ 1 and [Ag(OAc)L] _∞ 2, respectively. X-ray crystallographic studies showed that the ligand adopts a linear conformation in dimeric complex 1 and a bent conformation in polymeric complex 2. Both compounds exhibited temperature-dependent ³¹P{¹H} NMR spectra.

Original language	English
Pages (from-to)	1315-1318
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	6
Issue number	10
DOIs	https://doi.org/10.1016/j.inoche.2003.08.007
Publication status	Published - 1 Oct 2003

Scopus Subject Areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

User-Defined Keywords

Bis(ethylamidophosphine)
Crystal structure
Silver(I) complex
Temperature-dependent P{H} NMR study

Access to Document

10.1016/j.inoche.2003.08.007

Cite this

@article{e8c7624711b44631b3223688f9324991,

title = "Synthesis and characterization of silver(I) complexes [AgL] 2[BF4]2 and [Ag(OAc)L]∞ [L = (CH2NHCOC2H4PPh2)2]",

abstract = "The interaction of (CH2NHCOC2H4PPh 2)2, L, with one equivalent of AgBF4 and AgOAc gave [AgL]2[BF4]2 1 and [Ag(OAc)L] ∞ 2, respectively. X-ray crystallographic studies showed that the ligand adopts a linear conformation in dimeric complex 1 and a bent conformation in polymeric complex 2. Both compounds exhibited temperature-dependent 31P{1H} NMR spectra.",

keywords = "Bis(ethylamidophosphine), Crystal structure, Silver(I) complex, Temperature-dependent P{H} NMR study",

author = "Yat Li and Yung, {Ka Fu} and Chan, {Hoi Shan} and Wong, {Wing Tak} and WONG, {Rick W K} and Tse, {Man Chung}",

note = "Funding Information: Y. Li, K.-F Yung, H.-S. Chan, and W.-T. Wong thank the Hong Kong Research Grants Council and the University of Hong Kong for financial support. M.-C. Tse and W.-K. Wong thank the Hong Kong Baptist University and the Hong Kong Research Grants Council for financial support.",

year = "2003",

month = oct,

day = "1",

doi = "10.1016/j.inoche.2003.08.007",

language = "English",

volume = "6",

pages = "1315--1318",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier BV",

number = "10",

}

TY - JOUR

T1 - Synthesis and characterization of silver(I) complexes [AgL] 2[BF4]2 and [Ag(OAc)L]∞ [L = (CH2NHCOC2H4PPh2)2]

AU - Li, Yat

AU - Yung, Ka Fu

AU - Chan, Hoi Shan

AU - Wong, Wing Tak

AU - WONG, Rick W K

AU - Tse, Man Chung

N1 - Funding Information: Y. Li, K.-F Yung, H.-S. Chan, and W.-T. Wong thank the Hong Kong Research Grants Council and the University of Hong Kong for financial support. M.-C. Tse and W.-K. Wong thank the Hong Kong Baptist University and the Hong Kong Research Grants Council for financial support.

PY - 2003/10/1

Y1 - 2003/10/1

N2 - The interaction of (CH2NHCOC2H4PPh 2)2, L, with one equivalent of AgBF4 and AgOAc gave [AgL]2[BF4]2 1 and [Ag(OAc)L] ∞ 2, respectively. X-ray crystallographic studies showed that the ligand adopts a linear conformation in dimeric complex 1 and a bent conformation in polymeric complex 2. Both compounds exhibited temperature-dependent 31P{1H} NMR spectra.

AB - The interaction of (CH2NHCOC2H4PPh 2)2, L, with one equivalent of AgBF4 and AgOAc gave [AgL]2[BF4]2 1 and [Ag(OAc)L] ∞ 2, respectively. X-ray crystallographic studies showed that the ligand adopts a linear conformation in dimeric complex 1 and a bent conformation in polymeric complex 2. Both compounds exhibited temperature-dependent 31P{1H} NMR spectra.

KW - Bis(ethylamidophosphine)

KW - Crystal structure

KW - Silver(I) complex

KW - Temperature-dependent P{H} NMR study

UR - http://www.scopus.com/inward/record.url?scp=0141960382&partnerID=8YFLogxK

U2 - 10.1016/j.inoche.2003.08.007

DO - 10.1016/j.inoche.2003.08.007

M3 - Journal article

AN - SCOPUS:0141960382

SN - 1387-7003

VL - 6

SP - 1315

EP - 1318

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 10

ER -