Synthesis and characterization of silver(I) complexes [AgL] 2[BF4]2 and [Ag(OAc)L] [L = (CH2NHCOC2H4PPh2)2]

Yat Li, Ka Fu Yung, Hoi Shan Chan, Wing Tak Wong*, Rick W K WONG, Man Chung Tse

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

6 Citations (Scopus)

Abstract

The interaction of (CH2NHCOC2H4PPh 2)2, L, with one equivalent of AgBF4 and AgOAc gave [AgL]2[BF4]2 1 and [Ag(OAc)L] 2, respectively. X-ray crystallographic studies showed that the ligand adopts a linear conformation in dimeric complex 1 and a bent conformation in polymeric complex 2. Both compounds exhibited temperature-dependent 31P{1H} NMR spectra.

Original languageEnglish
Pages (from-to)1315-1318
Number of pages4
JournalInorganic Chemistry Communication
Volume6
Issue number10
DOIs
Publication statusPublished - 1 Oct 2003

Scopus Subject Areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

User-Defined Keywords

  • Bis(ethylamidophosphine)
  • Crystal structure
  • Silver(I) complex
  • Temperature-dependent P{H} NMR study

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