Synthesis and characterization of ruthenium diiminodiphosphine complexes. X-ray structure of trans-Ru(P2N2)Cl2 · 2H2O (P2N2 = N,N′-bis [o-(diphenylphosphino)benzylidene]ethylenediamine)

Wai Kwok Wong; Jing Xing Gao; Zhong Yuan Zhou; Thomas C.W. Mak

doi:10.1016/S0277-5387(00)84336-3

Synthesis and characterization of ruthenium diiminodiphosphine complexes. X-ray structure of trans-Ru(P₂N₂)Cl₂ · 2H₂O (P₂N₂ = N,N′-bis [o-(diphenylphosphino)benzylidene]ethylenediamine)

Wai Kwok Wong^*
, Jing Xing Gao
, Zhong Yuan Zhou
, Thomas C.W. Mak

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

24 Citations (Scopus)

Abstract

The interaction of Ru(OAc)₂(Ph₃P)₂ with 1 equivalent of N,N′-bis[o-(diphenylphosphino)benzylidene]ethylenediamine (P₂N₂) in refluxing dichloromethane gives trans-Ru(OAc)₂(P₂N₂) (I) in moderate yield (63%); in refluxing toluene the reaction gives a red product, which upon recrystallization in CHCl₃/hexane gives trans-Ru(OAc)₂Cl₂·2H₂O (III) in good yield (92%). Compounds I and III have been fully characterized by analytical and spectroscopic methods. The structure of III has been determined by an X-ray diffraction study.

Original language	English
Pages (from-to)	1415-1417
Number of pages	3
Journal	Polyhedron
Volume	12
Issue number	11
DOIs	https://doi.org/10.1016/S0277-5387(00)84336-3
Publication status	Published - Jun 1993

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@article{f596c6dedccf486596db1766e334ca31,

title = "Synthesis and characterization of ruthenium diiminodiphosphine complexes. X-ray structure of trans-Ru(P2N2)Cl2 · 2H2O (P2N2 = N,N′-bis [o-(diphenylphosphino)benzylidene]ethylenediamine)",

abstract = "The interaction of Ru(OAc)2(Ph3P)2 with 1 equivalent of N,N′-bis[o-(diphenylphosphino)benzylidene]ethylenediamine (P2N2) in refluxing dichloromethane gives trans-Ru(OAc)2(P2N2) (I) in moderate yield (63\%); in refluxing toluene the reaction gives a red product, which upon recrystallization in CHCl3/hexane gives trans-Ru(OAc)2Cl2·2H2O (III) in good yield (92\%). Compounds I and III have been fully characterized by analytical and spectroscopic methods. The structure of III has been determined by an X-ray diffraction study.",

author = "Wong, \{Wai Kwok\} and Gao, \{Jing Xing\} and Zhou, \{Zhong Yuan\} and Mak, \{Thomas C.W.\}",

year = "1993",

month = jun,

doi = "10.1016/S0277-5387(00)84336-3",

language = "English",

volume = "12",

pages = "1415--1417",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier Ltd.",

number = "11",

}

Synthesis and characterization of ruthenium diiminodiphosphine complexes. X-ray structure of trans-Ru(P₂N₂)Cl₂ · 2H₂O (P₂N₂ = N,N′-bis [o-(diphenylphosphino)benzylidene]ethylenediamine). / Wong, Wai Kwok; Gao, Jing Xing; Zhou, Zhong Yuan et al.
In: Polyhedron, Vol. 12, No. 11, 06.1993, p. 1415-1417.

Research output: Contribution to journal › Journal article › peer-review

TY - JOUR

T1 - Synthesis and characterization of ruthenium diiminodiphosphine complexes. X-ray structure of trans-Ru(P2N2)Cl2 · 2H2O (P2N2 = N,N′-bis [o-(diphenylphosphino)benzylidene]ethylenediamine)

AU - Wong, Wai Kwok

AU - Gao, Jing Xing

AU - Zhou, Zhong Yuan

AU - Mak, Thomas C.W.

PY - 1993/6

Y1 - 1993/6

N2 - The interaction of Ru(OAc)2(Ph3P)2 with 1 equivalent of N,N′-bis[o-(diphenylphosphino)benzylidene]ethylenediamine (P2N2) in refluxing dichloromethane gives trans-Ru(OAc)2(P2N2) (I) in moderate yield (63%); in refluxing toluene the reaction gives a red product, which upon recrystallization in CHCl3/hexane gives trans-Ru(OAc)2Cl2·2H2O (III) in good yield (92%). Compounds I and III have been fully characterized by analytical and spectroscopic methods. The structure of III has been determined by an X-ray diffraction study.

AB - The interaction of Ru(OAc)2(Ph3P)2 with 1 equivalent of N,N′-bis[o-(diphenylphosphino)benzylidene]ethylenediamine (P2N2) in refluxing dichloromethane gives trans-Ru(OAc)2(P2N2) (I) in moderate yield (63%); in refluxing toluene the reaction gives a red product, which upon recrystallization in CHCl3/hexane gives trans-Ru(OAc)2Cl2·2H2O (III) in good yield (92%). Compounds I and III have been fully characterized by analytical and spectroscopic methods. The structure of III has been determined by an X-ray diffraction study.

UR - https://www.scopus.com/pages/publications/0001736711

U2 - 10.1016/S0277-5387(00)84336-3

DO - 10.1016/S0277-5387(00)84336-3

M3 - Journal article

AN - SCOPUS:0001736711

SN - 0277-5387

VL - 12

SP - 1415

EP - 1417

JO - Polyhedron

JF - Polyhedron

IS - 11

ER -

Synthesis and characterization of ruthenium diiminodiphosphine complexes. X-ray structure of trans-Ru(P₂N₂)Cl₂ · 2H₂O (P₂N₂ = N,N′-bis [o-(diphenylphosphino)benzylidene]ethylenediamine)

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