Synthesis and characterization of oxadisilole-fused-3,4-dihydro-2H- naphtho[2,1-e]-1,3-oxazines and 3,4-dihydro-2H-anthra[2,1-e]-1,3-oxazines

Di Xu, Yibei Lin, Yali Chen*, Jie Zhang, Weiguo Cao, Jie Chen, Ricky M S WONG

*Corresponding author for this work

Research output: Contribution to journalJournal articlepeer-review

8 Citations (Scopus)

Abstract

Oxadisilole-fused-3,4-dihydro-2H-naphtho[2,1-e]-1,3-oxazines and 3,4-dihydro-2H-anthra[2,1-e]-1,3-oxazines were synthesized through an eco-friendly Mannich type condensation-cyclization reaction of oxadisilole-fused-1-naphthalenol or 1-anthracenol with formaldehyde and primary amines at ambient temperature in high to excellent yields. The photophysical, electrochemical, and thermal properties of these 3,4-dihydro-2H-anthra[2,1-e]-1, 3-oxazine derivatives were also studied.

Original languageEnglish
Pages (from-to)6144-6149
Number of pages6
JournalTetrahedron
Volume69
Issue number30
DOIs
Publication statusPublished - 29 Jul 2013

Scopus Subject Areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

User-Defined Keywords

  • Anthracenol
  • Dihydro-2H-anthra[2,1-e]-1,3-oxazine
  • Dihydro-2H-naphtho[2,1-e]-1, 3-oxazine
  • Mannich condensation
  • Naphthalenol

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