Synthesis and characterization of chiral diimino- and diaminodiphosphine complexes of ruthenium. X-ray crystal structure of trans-RuCl2(1R,2R-cyclohexyl-P2N2) · C6H5CH3

Rick W K WONG; Tat Wai Chik; Xue Feng; Thomas C.W. Mak

doi:10.1016/0277-5387(96)00154-4

Synthesis and characterization of chiral diimino- and diaminodiphosphine complexes of ruthenium. X-ray crystal structure of trans-RuCl₂(1R,2R-cyclohexyl-P₂N₂) · C₆H₅CH₃

Rick W K WONG^*
, Tat Wai Chik
, Xue Feng
, Thomas C.W. Mak

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

10 Citations (Scopus)

Abstract

The interaction of RuCl₂(DMSO)₄ with 1 equivalent of 1R,2R-cyclohexyl-P₂N₂ and 1R,2R-cyclohexyl-P₂N₂H₄ in refluxing toluene gave trans-RuC₂(1R,2R-cyclohexyl-P₂N₂) (I) and trans-RuCl₂(1R,2R-cyclohexyl-P₂N₂H₄) (II) in 80% and 75% yields, respectively. Compounds I and II have been fully characterized by analytical and spectroscopic methods. The structure of II has been established by an X-ray diffraction study.

Original language	English
Pages (from-to)	3905-3907
Number of pages	3
Journal	Polyhedron
Volume	15
Issue number	21
DOIs	https://doi.org/10.1016/0277-5387(96)00154-4
Publication status	Published - 5 Aug 1996

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@article{565109072bac40dea2c937c5501febbe,

title = "Synthesis and characterization of chiral diimino- and diaminodiphosphine complexes of ruthenium. X-ray crystal structure of trans-RuCl2(1R,2R-cyclohexyl-P2N2) · C6H5CH3",

abstract = "The interaction of RuCl2(DMSO)4 with 1 equivalent of 1R,2R-cyclohexyl-P2N2 and 1R,2R-cyclohexyl-P2N2H4 in refluxing toluene gave trans-RuC2(1R,2R-cyclohexyl-P2N2) (I) and trans-RuCl2(1R,2R-cyclohexyl-P2N2H4) (II) in 80\% and 75\% yields, respectively. Compounds I and II have been fully characterized by analytical and spectroscopic methods. The structure of II has been established by an X-ray diffraction study.",

author = "WONG, \{Rick W K\} and Chik, \{Tat Wai\} and Xue Feng and Mak, \{Thomas C.W.\}",

note = "Funding Information: A\textasciitilde{}knok/rdgen?mrs--W.-K.W. thanks the Hong Kong Baptist University and the Hong Kong Research Grant Council for financial support.",

year = "1996",

month = aug,

day = "5",

doi = "10.1016/0277-5387(96)00154-4",

language = "English",

volume = "15",

pages = "3905--3907",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier Ltd.",

number = "21",

}

TY - JOUR

T1 - Synthesis and characterization of chiral diimino- and diaminodiphosphine complexes of ruthenium. X-ray crystal structure of trans-RuCl2(1R,2R-cyclohexyl-P2N2) · C6H5CH3

AU - WONG, Rick W K

AU - Chik, Tat Wai

AU - Feng, Xue

AU - Mak, Thomas C.W.

N1 - Funding Information: A~knok/rdgen?mrs--W.-K.W. thanks the Hong Kong Baptist University and the Hong Kong Research Grant Council for financial support.

PY - 1996/8/5

Y1 - 1996/8/5

N2 - The interaction of RuCl2(DMSO)4 with 1 equivalent of 1R,2R-cyclohexyl-P2N2 and 1R,2R-cyclohexyl-P2N2H4 in refluxing toluene gave trans-RuC2(1R,2R-cyclohexyl-P2N2) (I) and trans-RuCl2(1R,2R-cyclohexyl-P2N2H4) (II) in 80% and 75% yields, respectively. Compounds I and II have been fully characterized by analytical and spectroscopic methods. The structure of II has been established by an X-ray diffraction study.

AB - The interaction of RuCl2(DMSO)4 with 1 equivalent of 1R,2R-cyclohexyl-P2N2 and 1R,2R-cyclohexyl-P2N2H4 in refluxing toluene gave trans-RuC2(1R,2R-cyclohexyl-P2N2) (I) and trans-RuCl2(1R,2R-cyclohexyl-P2N2H4) (II) in 80% and 75% yields, respectively. Compounds I and II have been fully characterized by analytical and spectroscopic methods. The structure of II has been established by an X-ray diffraction study.

UR - https://www.scopus.com/pages/publications/0000897769

U2 - 10.1016/0277-5387(96)00154-4

DO - 10.1016/0277-5387(96)00154-4

M3 - Journal article

AN - SCOPUS:0000897769

SN - 0277-5387

VL - 15

SP - 3905

EP - 3907

JO - Polyhedron

JF - Polyhedron

IS - 21

ER -

Synthesis and characterization of chiral diimino- and diaminodiphosphine complexes of ruthenium. X-ray crystal structure of trans-RuCl₂(1R,2R-cyclohexyl-P₂N₂) · C₆H₅CH₃

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