Synthesis and characterisation of tetraosmium carbonyl clusters bearing an azo type ligand: Crystal and molecular structures of [Os4(μ-H)4(CO)11(NC5H 4N=NPh)] and [Os4(μ-H)4(CO)10(MeCN)(NC5H 4N=NPh)]

Kelvin S Y Leung; Yat Li

doi:10.1016/S1387-7003(99)00162-8

Synthesis and characterisation of tetraosmium carbonyl clusters bearing an azo type ligand: Crystal and molecular structures of [Os4(μ-H)4(CO)11(NC5H 4N=NPh)] and [Os4(μ-H)4(CO)10(MeCN)(NC5H 4N=NPh)]

Kelvin S Y Leung^*, Yat Li

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

7 Citations (Scopus)

Abstract

Reaction of [Os4(μ-H)4(CO)10(MeCN)2] with one equivalent of 4-phenylazopyridine (4-PAP) in CH2Cl2 at ambient conditions afforded two new tetraosmium clusters [Os4(μ-H)4(CO)11(NC5H 4N=NPh)] (1) and [Os4(μ-H)4(CO)10(MeCN)(NC5H 4N=NPh)] (2) in moderate yields. Compound 1 exists as a pair of isomers in solution, which differ in the location of the bridging hydride ligands. The molecular structures of clusters 1 and 2 consist of a highly distorted tetrahedral metal skeleton, with the azo ligand terminally bonded to an osmium atom.

Original language	English
Pages (from-to)	599-603
Number of pages	5
Journal	Inorganic Chemistry Communications
Volume	2
Issue number	12
DOIs	https://doi.org/10.1016/S1387-7003(99)00162-8
Publication status	Published - Dec 1999

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title = "Synthesis and characterisation of tetraosmium carbonyl clusters bearing an azo type ligand: Crystal and molecular structures of [Os4(μ-H)4(CO)11(NC5H 4N=NPh)] and [Os4(μ-H)4(CO)10(MeCN)(NC5H 4N=NPh)]",

abstract = "Reaction of [Os4(μ-H)4(CO)10(MeCN)2] with one equivalent of 4-phenylazopyridine (4-PAP) in CH2Cl2 at ambient conditions afforded two new tetraosmium clusters [Os4(μ-H)4(CO)11(NC5H 4N=NPh)] (1) and [Os4(μ-H)4(CO)10(MeCN)(NC5H 4N=NPh)] (2) in moderate yields. Compound 1 exists as a pair of isomers in solution, which differ in the location of the bridging hydride ligands. The molecular structures of clusters 1 and 2 consist of a highly distorted tetrahedral metal skeleton, with the azo ligand terminally bonded to an osmium atom.",

author = "Leung, {Kelvin S Y} and Yat Li",

year = "1999",

month = dec,

doi = "10.1016/S1387-7003(99)00162-8",

language = "English",

volume = "2",

pages = "599--603",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

number = "12",

}

Synthesis and characterisation of tetraosmium carbonyl clusters bearing an azo type ligand: Crystal and molecular structures of [Os4(μ-H)4(CO)11(NC5H 4N=NPh)] and [Os4(μ-H)4(CO)10(MeCN)(NC5H 4N=NPh)]. / Leung, Kelvin S Y; Li, Yat.
In: Inorganic Chemistry Communications, Vol. 2, No. 12, 12.1999, p. 599-603.

Research output: Contribution to journal › Journal article › peer-review

TY - JOUR

T1 - Synthesis and characterisation of tetraosmium carbonyl clusters bearing an azo type ligand: Crystal and molecular structures of [Os4(μ-H)4(CO)11(NC5H 4N=NPh)] and [Os4(μ-H)4(CO)10(MeCN)(NC5H 4N=NPh)]

AU - Leung, Kelvin S Y

AU - Li, Yat

PY - 1999/12

Y1 - 1999/12

N2 - Reaction of [Os4(μ-H)4(CO)10(MeCN)2] with one equivalent of 4-phenylazopyridine (4-PAP) in CH2Cl2 at ambient conditions afforded two new tetraosmium clusters [Os4(μ-H)4(CO)11(NC5H 4N=NPh)] (1) and [Os4(μ-H)4(CO)10(MeCN)(NC5H 4N=NPh)] (2) in moderate yields. Compound 1 exists as a pair of isomers in solution, which differ in the location of the bridging hydride ligands. The molecular structures of clusters 1 and 2 consist of a highly distorted tetrahedral metal skeleton, with the azo ligand terminally bonded to an osmium atom.

AB - Reaction of [Os4(μ-H)4(CO)10(MeCN)2] with one equivalent of 4-phenylazopyridine (4-PAP) in CH2Cl2 at ambient conditions afforded two new tetraosmium clusters [Os4(μ-H)4(CO)11(NC5H 4N=NPh)] (1) and [Os4(μ-H)4(CO)10(MeCN)(NC5H 4N=NPh)] (2) in moderate yields. Compound 1 exists as a pair of isomers in solution, which differ in the location of the bridging hydride ligands. The molecular structures of clusters 1 and 2 consist of a highly distorted tetrahedral metal skeleton, with the azo ligand terminally bonded to an osmium atom.

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U2 - 10.1016/S1387-7003(99)00162-8

DO - 10.1016/S1387-7003(99)00162-8

M3 - Journal article

SN - 1387-7003

VL - 2

SP - 599

EP - 603

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 12

ER -

Synthesis and characterisation of tetraosmium carbonyl clusters bearing an azo type ligand: Crystal and molecular structures of [Os4(μ-H)4(CO)11(NC5H 4N=NPh)] and [Os4(μ-H)4(CO)10(MeCN)(NC5H 4N=NPh)]

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