Structure, resolution and chiroptical analysis of stable lanthanide complexes of a pyridylphenylphosphinate triazacyclononane ligand

  • James W. Walton
  • , Lorenzo Di Bari
  • , David Parker*
  • , Gennaro Pescitelli
  • , Horst Puschmann
  • , Dmitry S. Yufit
  • *Corresponding author for this work

Research output: Contribution to journalJournal articlepeer-review

41 Citations (Scopus)

Abstract

Lanthanide complexes of a pyridylphenylphosphinate ligand based on triazacyclononane form an isostructural series. The C3-symmetric Δ and Λ complexes of Eu and Tb are strongly emissive and can be resolved by chiral HPLC; the absolute configuration of each complex has been assigned using CD and CPL measurements.

Original languageEnglish
Pages (from-to)12289-12291
Number of pages3
JournalChemical Communications
Volume47
Issue number45
Early online date19 Oct 2011
DOIs
Publication statusPublished - 7 Dec 2011

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