Structure and NIR luminescence of lanthanide(III) complexes with an organic tridentate ligand

Bao Li An; Jian Song; Kok Wai CHEAH; Yuan Yuan Ren; Zhi Xuan Cheng

doi:10.1016/j.ica.2009.02.024

Structure and NIR luminescence of lanthanide(III) complexes with an organic tridentate ligand

Bao Li An^*, Jian Song, Kok Wai CHEAH, Yuan Yuan Ren, Zhi Xuan Cheng

^*Corresponding author for this work

Department of Physics

Research output: Contribution to journal › Journal article › peer-review

12 Citations (Scopus)

Abstract

Some lanthanide (Ln) complexes (Ln = Er, Nd, Yb) with an organic ligand, 6-diphenylamine carbonyl 2-pyridine carboxylic acid (HDPAP), have been synthesized. The crystal structure and near infrared luminescence of these complexes (Er-DPAP, Nd-DPAP and Yb-DPAP) have been investigated. The results showed that the lanthanide complexes have electroneutral structures and the near infrared (NIR) emission exhibits characteristic narrow emission of the lanthanide ions. The energy transfer mechanisms in the lanthanide complexes were discussed.

Original language	English
Pages (from-to)	3196-3200
Number of pages	5
Journal	Inorganica Chimica Acta
Volume	362
Issue number	9
DOIs	https://doi.org/10.1016/j.ica.2009.02.024
Publication status	Published - 1 Jul 2009

Scopus Subject Areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

User-Defined Keywords

Erbium complex
Luminescence
Neodymium complex
X-ray crystallography
Ytterbium complex

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10.1016/j.ica.2009.02.024

Cite this

@article{503d9f044fa046f8a89af0981952ed03,

title = "Structure and NIR luminescence of lanthanide(III) complexes with an organic tridentate ligand",

abstract = "Some lanthanide (Ln) complexes (Ln = Er, Nd, Yb) with an organic ligand, 6-diphenylamine carbonyl 2-pyridine carboxylic acid (HDPAP), have been synthesized. The crystal structure and near infrared luminescence of these complexes (Er-DPAP, Nd-DPAP and Yb-DPAP) have been investigated. The results showed that the lanthanide complexes have electroneutral structures and the near infrared (NIR) emission exhibits characteristic narrow emission of the lanthanide ions. The energy transfer mechanisms in the lanthanide complexes were discussed.",

keywords = "Erbium complex, Luminescence, Neodymium complex, X-ray crystallography, Ytterbium complex",

author = "An, {Bao Li} and Jian Song and CHEAH, {Kok Wai} and Ren, {Yuan Yuan} and Cheng, {Zhi Xuan}",

note = "Funding Information: This work was supported by the fund of Shanghai Municipal Education Committee (2006AZ071), Systems Biology Research Foundation of Shanghai University and Fund of Fifth Key Discipline of Shanghai Education Committee (No. J50102). ",

year = "2009",

month = jul,

day = "1",

doi = "10.1016/j.ica.2009.02.024",

language = "English",

volume = "362",

pages = "3196--3200",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier BV",

number = "9",

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TY - JOUR

T1 - Structure and NIR luminescence of lanthanide(III) complexes with an organic tridentate ligand

AU - An, Bao Li

AU - Song, Jian

AU - CHEAH, Kok Wai

AU - Ren, Yuan Yuan

AU - Cheng, Zhi Xuan

N1 - Funding Information: This work was supported by the fund of Shanghai Municipal Education Committee (2006AZ071), Systems Biology Research Foundation of Shanghai University and Fund of Fifth Key Discipline of Shanghai Education Committee (No. J50102).

PY - 2009/7/1

Y1 - 2009/7/1

N2 - Some lanthanide (Ln) complexes (Ln = Er, Nd, Yb) with an organic ligand, 6-diphenylamine carbonyl 2-pyridine carboxylic acid (HDPAP), have been synthesized. The crystal structure and near infrared luminescence of these complexes (Er-DPAP, Nd-DPAP and Yb-DPAP) have been investigated. The results showed that the lanthanide complexes have electroneutral structures and the near infrared (NIR) emission exhibits characteristic narrow emission of the lanthanide ions. The energy transfer mechanisms in the lanthanide complexes were discussed.

AB - Some lanthanide (Ln) complexes (Ln = Er, Nd, Yb) with an organic ligand, 6-diphenylamine carbonyl 2-pyridine carboxylic acid (HDPAP), have been synthesized. The crystal structure and near infrared luminescence of these complexes (Er-DPAP, Nd-DPAP and Yb-DPAP) have been investigated. The results showed that the lanthanide complexes have electroneutral structures and the near infrared (NIR) emission exhibits characteristic narrow emission of the lanthanide ions. The energy transfer mechanisms in the lanthanide complexes were discussed.

KW - Erbium complex

KW - Luminescence

KW - Neodymium complex

KW - X-ray crystallography

KW - Ytterbium complex

UR - http://www.scopus.com/inward/record.url?scp=67349199940&partnerID=8YFLogxK

U2 - 10.1016/j.ica.2009.02.024

DO - 10.1016/j.ica.2009.02.024

M3 - Journal article

AN - SCOPUS:67349199940

SN - 0020-1693

VL - 362

SP - 3196

EP - 3200

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 9

ER -

Structure and NIR luminescence of lanthanide(III) complexes with an organic tridentate ligand

Abstract

Scopus Subject Areas

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