Structure and dynamics of all of the stereoisomers of europium complexes of tetra(carboxyethyl) derivatives of dota: Ring inversion is decoupled from cooperative arm rotation in the RRRR and RRRS isomers

Judith A.K. Howard; Alan M. Kenwright; Janet M. Moloney; David Parker; Marc Port; Michel Navet; Olivier Rousseau; Mark Woods

doi:10.1039/a802847h

Structure and dynamics of all of the stereoisomers of europium complexes of tetra(carboxyethyl) derivatives of dota: Ring inversion is decoupled from cooperative arm rotation in the RRRR and RRRS isomers

Judith A.K. Howard
, Alan M. Kenwright
, Janet M. Moloney
, David Parker^*
, Marc Port
, Michel Navet
, Olivier Rousseau
, Mark Woods

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

94 Citations (Scopus)

Abstract

The absolute configuration of the four stereoisomeric α-substituted derivatives of dota has been defined; in their Eu complexes, 2D-NMR methods have revealed that in solution ring inversion is independent of pendant arm rotation and the (RRRR)-[EuL^1a] complex which in the solid state crystallises as a square antiprismatic structure.

Original language	English
Pages (from-to)	1381-1382
Number of pages	2
Journal	Chemical Communications
Issue number	13
DOIs	https://doi.org/10.1039/a802847h
Publication status	Published - 7 Jul 1998

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10.1039/a802847h

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Howard, J. A. K., Kenwright, A. M., Moloney, J. M., Parker, D., Port, M., Navet, M., Rousseau, O., & Woods, M. (1998). Structure and dynamics of all of the stereoisomers of europium complexes of tetra(carboxyethyl) derivatives of dota: Ring inversion is decoupled from cooperative arm rotation in the RRRR and RRRS isomers. Chemical Communications, (13), 1381-1382. https://doi.org/10.1039/a802847h

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title = "Structure and dynamics of all of the stereoisomers of europium complexes of tetra(carboxyethyl) derivatives of dota: Ring inversion is decoupled from cooperative arm rotation in the RRRR and RRRS isomers",

abstract = "The absolute configuration of the four stereoisomeric α-substituted derivatives of dota has been defined; in their Eu complexes, 2D-NMR methods have revealed that in solution ring inversion is independent of pendant arm rotation and the (RRRR)-[EuL1a] complex which in the solid state crystallises as a square antiprismatic structure.",

author = "Howard, \{Judith A.K.\} and Kenwright, \{Alan M.\} and Moloney, \{Janet M.\} and David Parker and Marc Port and Michel Navet and Olivier Rousseau and Mark Woods",

note = "We thank EPSRC for support.",

year = "1998",

month = jul,

day = "7",

doi = "10.1039/a802847h",

language = "English",

pages = "1381--1382",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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}

Howard, JAK, Kenwright, AM, Moloney, JM, Parker, D, Port, M, Navet, M, Rousseau, O & Woods, M 1998, 'Structure and dynamics of all of the stereoisomers of europium complexes of tetra(carboxyethyl) derivatives of dota: Ring inversion is decoupled from cooperative arm rotation in the RRRR and RRRS isomers', Chemical Communications, no. 13, pp. 1381-1382. https://doi.org/10.1039/a802847h

Structure and dynamics of all of the stereoisomers of europium complexes of tetra(carboxyethyl) derivatives of dota: Ring inversion is decoupled from cooperative arm rotation in the RRRR and RRRS isomers. / Howard, Judith A.K.; Kenwright, Alan M.; Moloney, Janet M. et al.
In: Chemical Communications, No. 13, 07.07.1998, p. 1381-1382.

Research output: Contribution to journal › Journal article › peer-review

TY - JOUR

T1 - Structure and dynamics of all of the stereoisomers of europium complexes of tetra(carboxyethyl) derivatives of dota

T2 - Ring inversion is decoupled from cooperative arm rotation in the RRRR and RRRS isomers

AU - Howard, Judith A.K.

AU - Kenwright, Alan M.

AU - Moloney, Janet M.

AU - Parker, David

AU - Port, Marc

AU - Navet, Michel

AU - Rousseau, Olivier

AU - Woods, Mark

N1 - We thank EPSRC for support.

PY - 1998/7/7

Y1 - 1998/7/7

N2 - The absolute configuration of the four stereoisomeric α-substituted derivatives of dota has been defined; in their Eu complexes, 2D-NMR methods have revealed that in solution ring inversion is independent of pendant arm rotation and the (RRRR)-[EuL1a] complex which in the solid state crystallises as a square antiprismatic structure.

AB - The absolute configuration of the four stereoisomeric α-substituted derivatives of dota has been defined; in their Eu complexes, 2D-NMR methods have revealed that in solution ring inversion is independent of pendant arm rotation and the (RRRR)-[EuL1a] complex which in the solid state crystallises as a square antiprismatic structure.

UR - https://www.scopus.com/pages/publications/0002431844

U2 - 10.1039/a802847h

DO - 10.1039/a802847h

M3 - Journal article

AN - SCOPUS:0002431844

SN - 1359-7345

SP - 1381

EP - 1382

JO - Chemical Communications

JF - Chemical Communications

IS - 13

ER -

Structure and dynamics of all of the stereoisomers of europium complexes of tetra(carboxyethyl) derivatives of dota: Ring inversion is decoupled from cooperative arm rotation in the RRRR and RRRS isomers

Abstract

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