Structural characterisation of a diprotonated ligand lanthanide complex - A key intermediate in lanthanide ion association and complex dissociation pathways

Philip A. Stenson; Amber L. Thompson; David Parker

doi:10.1039/b605876k

Structural characterisation of a diprotonated ligand lanthanide complex - A key intermediate in lanthanide ion association and complex dissociation pathways

Philip A. Stenson
, Amber L. Thompson
, David Parker^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

19 Citations (Scopus)

Abstract

The X-ray structure is reported of a diprotonated Gd(iii) tetra-aqua complex of the ligand 1,4,7,10-tetrakis(carbamoylmethyl)-1,4,7,10-tetraazacyclododecane (DOTAM), a thermodynamic intermediate in metal ion association and dissociation pathways.

Original language	English
Pages (from-to)	3291-3293
Number of pages	3
Journal	Dalton Transactions
Issue number	27
DOIs	https://doi.org/10.1039/b605876k
Publication status	Published - 31 May 2006

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@article{115b3562b8934a9c9941575f77019079,

title = "Structural characterisation of a diprotonated ligand lanthanide complex - A key intermediate in lanthanide ion association and complex dissociation pathways",

abstract = "The X-ray structure is reported of a diprotonated Gd(iii) tetra-aqua complex of the ligand 1,4,7,10-tetrakis(carbamoylmethyl)-1,4,7,10-tetraazacyclododecane (DOTAM), a thermodynamic intermediate in metal ion association and dissociation pathways.",

author = "Stenson, \{Philip A.\} and Thompson, \{Amber L.\} and David Parker",

note = "We thank Durham University and the EPSRC for support, and Prof. J. A. K. Howard for useful discussions. Publisher copyright: {\textcopyright} The Royal Society of Chemistry 2006",

year = "2006",

month = may,

day = "31",

doi = "10.1039/b605876k",

language = "English",

pages = "3291--3293",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "27",

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TY - JOUR

T1 - Structural characterisation of a diprotonated ligand lanthanide complex - A key intermediate in lanthanide ion association and complex dissociation pathways

AU - Stenson, Philip A.

AU - Thompson, Amber L.

AU - Parker, David

PY - 2006/5/31

Y1 - 2006/5/31

N2 - The X-ray structure is reported of a diprotonated Gd(iii) tetra-aqua complex of the ligand 1,4,7,10-tetrakis(carbamoylmethyl)-1,4,7,10-tetraazacyclododecane (DOTAM), a thermodynamic intermediate in metal ion association and dissociation pathways.

AB - The X-ray structure is reported of a diprotonated Gd(iii) tetra-aqua complex of the ligand 1,4,7,10-tetrakis(carbamoylmethyl)-1,4,7,10-tetraazacyclododecane (DOTAM), a thermodynamic intermediate in metal ion association and dissociation pathways.

UR - https://www.scopus.com/pages/publications/33745593458

U2 - 10.1039/b605876k

DO - 10.1039/b605876k

M3 - Journal article

C2 - 16820839

AN - SCOPUS:33745593458

SN - 1477-9226

SP - 3291

EP - 3293

JO - Dalton Transactions

JF - Dalton Transactions

IS - 27

ER -

Structural characterisation of a diprotonated ligand lanthanide complex - A key intermediate in lanthanide ion association and complex dissociation pathways

Abstract

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