Strong coupling of super-hydrophilic and vacancy-rich g-C₃N₄ and LDH heterostructure for wastewater purification: Adsorption-driven oxidation

Adsorption and wettability are crucial components of catalytic oxidation. To increase the reactive oxygen species (ROS) generation/utilization efficiency of peroxymonosulfate (PMS) activators, defect engineering and 2D nanosheet characteristics were used to regulate electronic structures and expose more active sites. Two-dimensional (2D) super-hydrophilic heterostructure by connecting cobalt species modified nitrogen vacancy-rich g-C₃N₄ (V_n-CN) and LDH (V_n-CN/Co/LDH) with high-density active sites and multi-vacancies, as well as high conductivity and adsorbability, to expedite ROS generation. The degradation rate constant of ofloxacin (OFX) was 0.441 min⁻¹ via the V_n-CN/Co/LDH/PMS system, which was 1–2 orders greater than in the previous studies. Confirmation of the contribution ratios of various reactive oxygen species (ROS), SO₄^·- and ¹O₂ in bulk solution, O₂^·- on the catalyst surface was the most abundant ROS. The catalytic membrane was constructed utilizing Vn-CN/Co/LDH as the assembly element. The 2D membrane achieved the continuous effective discharge of OFX in the simulated water after 80 h/4 cycles of continuous flowing-through filtration-catalysis. This study provides fresh insights into designing a PMS activator for environmental remediation activated on demand.