Stilbazolium based zwitterionic chromophores for electro-optic polymers

Ilias Liakatas*, Ricky M S WONG, Christian Bosshard, Marcel Ehrensperger, Peter Günter

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

3 Citations (Scopus)

Abstract

A series of stilbazolium based zwitterionic chromophores was synthesized. They have very large dipole moment (up to μ = 13×10-29 Cm) and high molecular hyperpolarizability (up to β = 135×10-40 m4V-1). Guest-host polymer thin films of the best molecules were prepared and poled by corona discharge. Values of the nonlinear optical coefficient (d31 = 0.7 pm/V, at λ = 1.545 nm) at molecular concentrations of 5×1019 m-3, comparable to that of Disperse Red 1, were obtained. The good molecular characteristics and macroscopic performance of these chromophores combined with their good thermal stability make them promising candidates for side-chain electro-optic polymers.

Original languageEnglish
Pages (from-to)299-306
Number of pages8
JournalFerroelectrics
Volume202
Issue number1-4
DOIs
Publication statusPublished - 1997

Scopus Subject Areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics

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