Solution behaviour of a monooxorhenium(V) complex of 1,4,8,11-tetraazacyclotetradecane

David Parker; Partha S. Roy

doi:10.1016/S0020-1693(00)87510-6

Solution behaviour of a monooxorhenium(V) complex of 1,4,8,11-tetraazacyclotetradecane

David Parker^*
, Partha S. Roy

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

7 Citations (Scopus)

Abstract

The reaction of ReOCl₃(PPh₃)₂ with cyclam gives a macrocyclic monooxorhenium(V) complex, [ReO(cyclam)(OH₂)]Cl₃ (1). This exist as a monocation in aqueous solution in which the cyclam ligand is doubly deprotonated [ReO(C₁₀H₂₂N₄(OH₂)]⁺ (2), the structure of which has been defined with the aid of NMR, visible spectrophotometric and FAB mass spectrometric methods.

Original language	English
Pages (from-to)	251-253
Number of pages	3
Journal	Inorganica Chimica Acta
Volume	148
Issue number	2
DOIs	https://doi.org/10.1016/S0020-1693(00)87510-6
Publication status	Published - 15 Aug 1988

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@article{d8ef91b5203945c9ae7caacb3ce19971,

title = "Solution behaviour of a monooxorhenium(V) complex of 1,4,8,11-tetraazacyclotetradecane",

abstract = "The reaction of ReOCl3(PPh3)2 with cyclam gives a macrocyclic monooxorhenium(V) complex, [ReO(cyclam)(OH2)]Cl3 (1). This exist as a monocation in aqueous solution in which the cyclam ligand is doubly deprotonated [ReO(C10H22N4(OH2)]+ (2), the structure of which has been defined with the aid of NMR, visible spectrophotometric and FAB mass spectrometric methods.",

author = "David Parker and Roy, \{Partha S.\}",

year = "1988",

month = aug,

day = "15",

doi = "10.1016/S0020-1693(00)87510-6",

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volume = "148",

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journal = "Inorganica Chimica Acta",

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T1 - Solution behaviour of a monooxorhenium(V) complex of 1,4,8,11-tetraazacyclotetradecane

AU - Parker, David

AU - Roy, Partha S.

PY - 1988/8/15

Y1 - 1988/8/15

N2 - The reaction of ReOCl3(PPh3)2 with cyclam gives a macrocyclic monooxorhenium(V) complex, [ReO(cyclam)(OH2)]Cl3 (1). This exist as a monocation in aqueous solution in which the cyclam ligand is doubly deprotonated [ReO(C10H22N4(OH2)]+ (2), the structure of which has been defined with the aid of NMR, visible spectrophotometric and FAB mass spectrometric methods.

AB - The reaction of ReOCl3(PPh3)2 with cyclam gives a macrocyclic monooxorhenium(V) complex, [ReO(cyclam)(OH2)]Cl3 (1). This exist as a monocation in aqueous solution in which the cyclam ligand is doubly deprotonated [ReO(C10H22N4(OH2)]+ (2), the structure of which has been defined with the aid of NMR, visible spectrophotometric and FAB mass spectrometric methods.

UR - https://www.scopus.com/pages/publications/0347604762

U2 - 10.1016/S0020-1693(00)87510-6

DO - 10.1016/S0020-1693(00)87510-6

M3 - Journal article

AN - SCOPUS:0347604762

SN - 0020-1693

VL - 148

SP - 251

EP - 253

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 2

ER -

Solution behaviour of a monooxorhenium(V) complex of 1,4,8,11-tetraazacyclotetradecane

Abstract

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