Solid-state synthesis of cluster compound [MoCu3OS3(PPh3)3(CH3COO)] with its structure, reactivity and optical non-linearities

Dong Xiang Zeng; Wei Ji; Wing Tak Wong; Wai Yeung Wong; Xin Quan Xin

doi:10.1016/S0020-1693(98)00119-4

Solid-state synthesis of cluster compound [MoCu₃OS₃(PPh₃)₃(CH₃COO)] with its structure, reactivity and optical non-linearities

Dong Xiang Zeng, Wei Ji, Wing Tak Wong, Wai Yeung Wong, Xin Quan Xin^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

27 Citations (Scopus)

Abstract

A novel acetate-containing cluster compound [MoCu₃OS₃(PPh₃)J(CH₃COO ^-)] was synthesized via a low-heating solid-state synthetic method. For the first time, the O-containing ligand was introduced into the Mo(W)-Cu(Ag)-S clusters with the O atoms acting as the coordinating atoms. The structure of this compound has been characterized by X-ray diffraction: space group P-1,Z=4,R=0.052,R_w=0.058. A series of reactions manifest the possible role of the binuclear structure of Cu(CH₃COO)₂ H₂O in the synthetic process as well as the relative weak affinity of the acetate group for Cu(I) compared with that of the halogen atoms. Z-scan measurements show that this compound exhibits interesting non-linear optical (NLO) effects.

Original language	English
Pages (from-to)	172-177
Number of pages	6
Journal	Inorganica Chimica Acta
Volume	279
Issue number	2
DOIs	https://doi.org/10.1016/S0020-1693(98)00119-4
Publication status	Published - 1 Oct 1998

Scopus Subject Areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

User-Defined Keywords

Acetate complexes
Copper complexes
Crystal structures
Molybdemun complexes
Nonlinear optics
Sulfur complexes

Access to Document

10.1016/S0020-1693(98)00119-4

Cite this

@article{52dbded9c71749f888348c5768f340b4,

title = "Solid-state synthesis of cluster compound [MoCu3OS3(PPh3)3(CH3COO)] with its structure, reactivity and optical non-linearities",

abstract = "A novel acetate-containing cluster compound [MoCu3OS3(PPh3)J(CH3COO -)] was synthesized via a low-heating solid-state synthetic method. For the first time, the O-containing ligand was introduced into the Mo(W)-Cu(Ag)-S clusters with the O atoms acting as the coordinating atoms. The structure of this compound has been characterized by X-ray diffraction: space group P-1,Z=4,R=0.052,Rw=0.058. A series of reactions manifest the possible role of the binuclear structure of Cu(CH3COO)2 H2O in the synthetic process as well as the relative weak affinity of the acetate group for Cu(I) compared with that of the halogen atoms. Z-scan measurements show that this compound exhibits interesting non-linear optical (NLO) effects.",

keywords = "Acetate complexes, Copper complexes, Crystal structures, Molybdemun complexes, Nonlinear optics, Sulfur complexes",

author = "Zeng, {Dong Xiang} and Wei Ji and Wong, {Wing Tak} and Wong, {Wai Yeung} and Xin, {Xin Quan}",

year = "1998",

month = oct,

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doi = "10.1016/S0020-1693(98)00119-4",

language = "English",

volume = "279",

pages = "172--177",

journal = "Inorganica Chimica Acta",

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publisher = "Elsevier BV",

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TY - JOUR

T1 - Solid-state synthesis of cluster compound [MoCu3OS3(PPh3)3(CH3COO)] with its structure, reactivity and optical non-linearities

AU - Zeng, Dong Xiang

AU - Ji, Wei

AU - Wong, Wing Tak

AU - Wong, Wai Yeung

AU - Xin, Xin Quan

PY - 1998/10/1

Y1 - 1998/10/1

N2 - A novel acetate-containing cluster compound [MoCu3OS3(PPh3)J(CH3COO -)] was synthesized via a low-heating solid-state synthetic method. For the first time, the O-containing ligand was introduced into the Mo(W)-Cu(Ag)-S clusters with the O atoms acting as the coordinating atoms. The structure of this compound has been characterized by X-ray diffraction: space group P-1,Z=4,R=0.052,Rw=0.058. A series of reactions manifest the possible role of the binuclear structure of Cu(CH3COO)2 H2O in the synthetic process as well as the relative weak affinity of the acetate group for Cu(I) compared with that of the halogen atoms. Z-scan measurements show that this compound exhibits interesting non-linear optical (NLO) effects.

AB - A novel acetate-containing cluster compound [MoCu3OS3(PPh3)J(CH3COO -)] was synthesized via a low-heating solid-state synthetic method. For the first time, the O-containing ligand was introduced into the Mo(W)-Cu(Ag)-S clusters with the O atoms acting as the coordinating atoms. The structure of this compound has been characterized by X-ray diffraction: space group P-1,Z=4,R=0.052,Rw=0.058. A series of reactions manifest the possible role of the binuclear structure of Cu(CH3COO)2 H2O in the synthetic process as well as the relative weak affinity of the acetate group for Cu(I) compared with that of the halogen atoms. Z-scan measurements show that this compound exhibits interesting non-linear optical (NLO) effects.

KW - Acetate complexes

KW - Copper complexes

KW - Crystal structures

KW - Molybdemun complexes

KW - Nonlinear optics

KW - Sulfur complexes

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DO - 10.1016/S0020-1693(98)00119-4

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AN - SCOPUS:0001021060

SN - 0020-1693

VL - 279

SP - 172

EP - 177

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 2

ER -