Solid sodium stannate as a high-efficiency superbase catalyst for anti-Markovnikov hydroamination and hydroalkoxylation of electron-deficient olefins under mild conditions

Shuguo Zhang; Yudan Wei; Shuangfeng Yin; Chak Tong Au

doi:10.1016/j.catcom.2010.12.030

Solid sodium stannate as a high-efficiency superbase catalyst for anti-Markovnikov hydroamination and hydroalkoxylation of electron-deficient olefins under mild conditions

Shuguo Zhang, Yudan Wei, Shuangfeng Yin^*, Chak Tong Au

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

24 Citations (Scopus)

Abstract

A solid superbase with H- above 26.5 has been obtained through thermal treatment of sodium stannate hydrate. It was found to be an efficient catalyst for anti-Markovnikov hydroamination and hydroalkoxylation of electron-deficient olefins under mild conditions.

Original language	English
Pages (from-to)	712-716
Number of pages	5
Journal	Catalysis Communications
Volume	12
Issue number	8
DOIs	https://doi.org/10.1016/j.catcom.2010.12.030
Publication status	Published - 31 Mar 2011

Scopus Subject Areas

Catalysis
General Chemistry
Process Chemistry and Technology

User-Defined Keywords

Acrylonitrile
Anti-Markovnikov
Electron-deficient olefins
Sodium stannate
Solid superbase

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10.1016/j.catcom.2010.12.030

Cite this

@article{19cbc3190dd943a5a677dc0cbf4b4a6c,

title = "Solid sodium stannate as a high-efficiency superbase catalyst for anti-Markovnikov hydroamination and hydroalkoxylation of electron-deficient olefins under mild conditions",

abstract = "A solid superbase with H- above 26.5 has been obtained through thermal treatment of sodium stannate hydrate. It was found to be an efficient catalyst for anti-Markovnikov hydroamination and hydroalkoxylation of electron-deficient olefins under mild conditions.",

keywords = "Acrylonitrile, Anti-Markovnikov, Electron-deficient olefins, Sodium stannate, Solid superbase",

author = "Shuguo Zhang and Yudan Wei and Shuangfeng Yin and Au, {Chak Tong}",

note = "Funding Information: The financial supports of the National Natural Science Foundation of China (Grant No. 20873038 ), and the Doctoral Program Foundation of Institutions of Higher Education of China (Grant No. 200805320001 ) are gratefully acknowledged. C.T. Au thanks the Hunan University for an adjunct professorship. ",

year = "2011",

month = mar,

day = "31",

doi = "10.1016/j.catcom.2010.12.030",

language = "English",

volume = "12",

pages = "712--716",

journal = "Catalysis Communications",

issn = "1566-7367",

publisher = "Elsevier",

number = "8",

}

Solid sodium stannate as a high-efficiency superbase catalyst for anti-Markovnikov hydroamination and hydroalkoxylation of electron-deficient olefins under mild conditions. / Zhang, Shuguo; Wei, Yudan; Yin, Shuangfeng et al.
In: Catalysis Communications, Vol. 12, No. 8, 31.03.2011, p. 712-716.

Research output: Contribution to journal › Journal article › peer-review

TY - JOUR

T1 - Solid sodium stannate as a high-efficiency superbase catalyst for anti-Markovnikov hydroamination and hydroalkoxylation of electron-deficient olefins under mild conditions

AU - Zhang, Shuguo

AU - Wei, Yudan

AU - Yin, Shuangfeng

AU - Au, Chak Tong

N1 - Funding Information: The financial supports of the National Natural Science Foundation of China (Grant No. 20873038 ), and the Doctoral Program Foundation of Institutions of Higher Education of China (Grant No. 200805320001 ) are gratefully acknowledged. C.T. Au thanks the Hunan University for an adjunct professorship.

PY - 2011/3/31

Y1 - 2011/3/31

N2 - A solid superbase with H- above 26.5 has been obtained through thermal treatment of sodium stannate hydrate. It was found to be an efficient catalyst for anti-Markovnikov hydroamination and hydroalkoxylation of electron-deficient olefins under mild conditions.

AB - A solid superbase with H- above 26.5 has been obtained through thermal treatment of sodium stannate hydrate. It was found to be an efficient catalyst for anti-Markovnikov hydroamination and hydroalkoxylation of electron-deficient olefins under mild conditions.

KW - Acrylonitrile

KW - Anti-Markovnikov

KW - Electron-deficient olefins

KW - Sodium stannate

KW - Solid superbase

UR - http://www.scopus.com/inward/record.url?scp=78751648260&partnerID=8YFLogxK

U2 - 10.1016/j.catcom.2010.12.030

DO - 10.1016/j.catcom.2010.12.030

M3 - Journal article

AN - SCOPUS:78751648260

SN - 1566-7367

VL - 12

SP - 712

EP - 716

JO - Catalysis Communications

JF - Catalysis Communications

IS - 8

ER -

Solid sodium stannate as a high-efficiency superbase catalyst for anti-Markovnikov hydroamination and hydroalkoxylation of electron-deficient olefins under mild conditions

Abstract

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